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'Diazepinones' in keywords Facet   section ZfN Section B  [X]
Facet   Publication Year 1985  [X]
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1Author    Roberto Millini, Horst Kisch, Carl KrügerRequires cookie*
 Title    Iron Carbonyl Assisted Synthesis of l,2-Diazepin-3-ones from Cyclic Diazenes and Alkynes [1]  
 Abstract    , 2a, c are prepared by an iron carbonyl mediated reaction sequence from alkynes and cyclic 1,2-diazenes. The latter are first converted into hexacarbonyl diiron complexes which react with two molecules of an alkyne to afford tricyclic carbonyl iron compounds I —III. Oxidative degradation with bromine leads to these novel heterocycles whose structure is confirmed by an X-ray analysis of lb. 
  Reference    Z. Naturforsch. 40b, 187—192 (1985); received October 15 1984 
  Published    1985 
  Keywords    Diazepinones, Diazenes, Alkynes, Carbonyl-Iron Assistance Bicyclic l, 2-diazepin-3-ones la—c 
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 TEI-XML for    default:Reihe_B/40/ZNB-1985-40b-0187.pdf 
 Identifier    ZNB-1985-40b-0187 
 Volume    40