Go toArchive
Browse byFacets
Bookbag ( 0 )
'Diazenes' in keywords
Results  3 Items
Sorted by   
Publication Year
1994 (1)
1985 (1)
1981 (1)
1Author    H. Kisch, C. Krüger, A. TrautweinRequires cookie*
 Title    Übergangsmetallkomplexe von Diazenen, XVI [1] Struktur und Mößbauerdaten von (2.3-Diazanorbornen)Fe3(CO)9 Transition Metal Complexes of Diazenes, XVI [1] Structure and Mössbauer Data of (2,3-Diazanorbornene)Fe3(CO)g  
 Abstract    The molecular structure of (2,3-diazanorbornene)Fe3(CO)9 consists of a triangular Fe3(CO)g group bound to the diazene unit. The seven-coordinated Fe(CO)3 group forms two Fe-N bonds with lengths of 1.974 and 1.965 Ä, each of the two six-coordinated Fe(CO)3 groups has slightly shorter Fe-N-bonds of 1.898 and 1.903 Ä. One Fe-Fe distance, 2.612Ä, is longer than the two other ones, 2.572 and 2.582 A, which are in the range of typical single bonds. The presence of seven-and six-coordinated iron carbonyl groups is also demonstrated by the Mössbauer spectrum showing signals with quadrupole splittings of 1.23 and 0.78, 0.62 ± 0.01 mm/s, respectively. 
  Reference    Z. Naturforsch. 36b, 205—207 (1981); eingegangen am 2. Dezember 1980 
  Published    1981 
  Keywords    Diazenes, Iron Cluster, X-ray, Mössbauer Data 
  Similar Items    Find
 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-0205.pdf 
 Identifier    ZNB-1981-36b-0205 
 Volume    36 
2Author    Gerd Knitter, Ulrich Behrens, Enno Lork, Rüdiger MewsRequires cookie*
 Title    Perfluorbenzyl-Stickstoff-Derivate Perfluorobenzyl Nitrogen Derivatives  
 Abstract    In the HgF2-assisted addition of Cl2 and Br2 to C6F5CN the compounds C6F5CF=NX (3, 5: X = Cl, Br) and C6F5CF2NX2 (2, 4: X = Cl, Br) are formed. Photochemical decomposition of the dibromoamine (4) gives the diazene C6F5CF2-N=N -CF2C6F5 (6) in 31% yield. The struc­ ture of 6 has been determined by X-ray diffraction. 
  Reference    Z. Naturforsch. 49b, 233—237 (1994); eingegangen am 25. September 1993 
  Published    1994 
  Keywords    Bromofluorination, Chlorofluorination, NN-Dihaloamines, N-Haloimines, Diazenes 
  Similar Items    Find
 TEI-XML for    default:Reihe_B/49/ZNB-1994-49b-0233.pdf 
 Identifier    ZNB-1994-49b-0233 
 Volume    49 
3Author    Roberto Millini, Horst Kisch, Carl KrügerRequires cookie*
 Title    Iron Carbonyl Assisted Synthesis of l,2-Diazepin-3-ones from Cyclic Diazenes and Alkynes [1]  
 Abstract    , 2a, c are prepared by an iron carbonyl mediated reaction sequence from alkynes and cyclic 1,2-diazenes. The latter are first converted into hexacarbonyl diiron complexes which react with two molecules of an alkyne to afford tricyclic carbonyl iron compounds I —III. Oxidative degradation with bromine leads to these novel heterocycles whose structure is confirmed by an X-ray analysis of lb. 
  Reference    Z. Naturforsch. 40b, 187—192 (1985); received October 15 1984 
  Published    1985 
  Keywords    Diazepinones, Diazenes, Alkynes, Carbonyl-Iron Assistance Bicyclic l, 2-diazepin-3-ones la—c 
  Similar Items    Find
 TEI-XML for    default:Reihe_B/40/ZNB-1985-40b-0187.pdf 
 Identifier    ZNB-1985-40b-0187 
 Volume    40