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1999 (1)
1Author    Lothar Weber, Eckhard Dobbert, Andreas Rausch, Hans-Georg Stammler, Beate NeumannRequires cookie*
 Title    Synthesis, Structure and Reactivity of 2-Amino-and 2-Imino-2,3-dihydro-1H -1,3,2-diazaboroles  
 Abstract    The 2-halo-2,3-dihydro-1H-1,3,2-diazaboroles RN-CH=CH-N(R)BX (la': R = rBu, X = Br; lb: R = 2,6-Me2C6H.v, X = I) were converted into the 2-amino-2,3-dihydro-\H -1,3,2-diazaboroles RN-CH=CH-N(R)B-NH2 (2a: R = /Bu; 2b: 2,6-Me2C6H3) by treatment with dry gaseous ammonia. Similarly reaction of la' with 2,6-dimethylaniline or /BuNHt afforded the corresponding derivates /BuN-CH=CH-N(rBu)BNHR' (3; R 1 = 2,6-Me2C6H3; 4; R1 = rBu). The treatment of la' with the ethylene diamine adduct of lithium acetylide led to the formation of [rBuN-CH=CH-N(/Bu)BN(H)CH2]2 (5). Lithiation of 2 a and subsequent silylation gave 6 (R1 = SiMe3), which was transformed to the diborolylamine [/BuN-CH=CH-N(rBu)B]2NH (7) upon exposure to la'. Borolylketimine /BuN-CH=CH-N(/Bu)B-N=CPh2 (8) and borolylcar-bodiimide fBuN-CH=CHN(/Bu)B-N=C=N-SiMe3 (9) resulted from la' and Ph2C=NSiMe3 or Me3SiN=C=NSiMe3, respectively. All the new compounds were characterized by elemental analyses as well as spectroscopic data (IR, 'H, n B, i3C NMR, MS). Heterocycle 5 was also subjected to an X-ray diffraction analysis. 
  Reference    Z. Naturforsch. 54b, 363—371 (1999); eingegangen am 25. September 1998 
  Published    1999 
  Keywords    Boron, Diazaboroles, Amines, Imines 
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 TEI-XML for    default:Reihe_B/54/ZNB-1999-54b-0363.pdf 
 Identifier    ZNB-1999-54b-0363 
 Volume    54