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'Diastereoisomers' in keywords Facet   Publication Year 1980  [X]
Facet   section ZfN Section B  [X]
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1980[X]
1Author    Henri Brunner, Jean-Claude LeblancRequires cookie*
 Title    (CH2OCH3)P(C6H5)2N(CH3)R * mit chiralen Fe-Atomen Optically Active Transition Metal Complexes, LXX [1] Preparation of the Optically Active Diastereoisomers CsHsFe^O)- (CH2OCH3)P(C6H5)2N(CH3)R* with Chiral Fe Atoms  
 Abstract    The two diastereoisomers CsHsFe(CO)(CH2OCH3)P(CeHs)2N(CH3)R* (Ba, b), with R* = 0S)-CH(CH3)(C6H5), differing only in the Fe configuration, have been obtained by photochemical reaction of C5H5Fe(C0)2CH20CH3 with (£)-(+)-P(C6H5)2N(CH3)R*. The optically pure isomer 3 a can be isolated by chromatography at low temperature; its chiroptical properties are discussed. 
  Reference    Z. Naturforsch. 35b, 1491—1493 (1980); eingegangen am 8. August 1980 
  Published    1980 
  Keywords    Diastereoisomers, Fe-Configuration, Separation, CD Spectra 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-1491_n.pdf 
 Identifier    ZNB-1980-35b-1491_n 
 Volume    35