| 1 | Author
| Karl Hensena>, Markus Kettner3, T., Peter Pickel3, Michael Bolteb | Requires cookie* | | Title
| Neue dikationische Silicium-Komplexe mit N-Methylimidazol New Dicationic Silicon Complexes with N-M ethylimidazole  | | | Abstract
| The reactions of the dibromosilanes Et2SiBr2, Ph2SiBr2, EtHSiBr2, PhHSiBr2 and MeHSiBr2 with N-methylimidazole (NMI) led to white powders stable at room temperature (with Et2SiBr2 an 1:2 adduct, with EtHSiBr2 and Ph2SiBr2 1:3 adducts, and with PhHSiBr2 and MeHSiBr2 1:4 adducts). The compounds crystallize from solutions in chloroforme and acetonitrile. The X-ray single crystal investigations show in all five cases dicationic complexes. | | |
Reference
| Z. Naturforsch. 54b, 200—208 (1999); eingegangen am 8. Oktober 1998 | | |
Published
| 1999 | | |
Keywords
| Dialkyldibromosilanes, Alkyldibromosilanes, N-Methylimidazol, Lewis-Acid-Base-Adducts, Crystal Structure | | |
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| default:Reihe_B/54/ZNB-1999-54b-0200.pdf | | | Identifier
| ZNB-1999-54b-0200 | | | Volume
| 54 | |
|