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1976 (1)
1975 (1)
1Author    G. S.Requires cookie*
 Title    Reactions of tert-Butylperoxy Esters, XIII Reactions of Dialkyl ie/t-Butylperoxy Phosphates with A m inesa,b,c  
 Abstract    The interaction of dialkyl tert-butylperoxy phosphates, (R 0)2P (0)0 0 C M e3 (1) with primary and secondary cycloalkylamines, R 'R " N H , R' = cyclo-CeH^, R " = H ; R '= R " = cyclo-C6H n (2) in the presence and absence of water, produces the corre­ sponding dialkyl cycloalkyl ammonium phosphates, (R 0)2P (0) 0 -N +H 2R " R / (3), and ierJ-butanol. In carbon tetrachloride the reaction produces in addition to 3 the corre­ sponding cyclohexylammonium chloride, discussed. 
  Reference    (Z. Naturforsch. 30b, 724—731 [1975]; received February 17 1975) 
  Published    1975 
  Keywords    fer£-Butylperoxy Esters, Dialkyl Cycloalkylammonium Phosphates, feri-Butylperoxy Phosphates, Dialkyl Phosphates, Amines 
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 TEI-XML for    default:Reihe_B/30/ZNB-1975-30b-0724.pdf 
 Identifier    ZNB-1975-30b-0724 
 Volume    30 
2Author    G. Sosnovsky, E. H. ZaretRequires cookie*
 Title    Reactions of terf-Butylperoxy Esters. XV Decomposition of Dialkyl tert-Butylperoxy Phosphates 13  
 Abstract    Dialkyl The thermal decomposition of dialkyl £er£-butylperoxy phosphates, in the presence and absence of solvents, yields the corresponding dialkyl phosphate, acetone, methanol, 2,2-dimethoxypropane, and methyl isopropenyl ether as the primary products. Prolonged heating of the product mixture produces trialkyl phosphates, (R0)3P(0), which arise from the thermal decomposition of dialkyl phosphates. Data are presented to support a mechanism involving the heterolytic cleavage of the peroxide linkage. 
  Reference    (Z. Naturforsch. 31b, 820—831 [1976]; received November 20 1975) 
  Published    1976 
  Keywords    teri-Butylperoxy Phosphates, Tetraalkyl Pyrophosphates, Dialkyl Phosphates, Trialkyl Phosphates, Free Radicals 
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 TEI-XML for    default:Reihe_B/31/ZNB-1976-31b-0820.pdf 
 Identifier    ZNB-1976-31b-0820 
 Volume    31