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'Depolymerisation' in keywords Facet   section ZfN Section B  [X]
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1994 (1)
1Author    RolfW. Saalfrank3, Oliver Struck3, Karl Petersb, HansG. Eorg, Von SchneringbRequires cookie*
 Title    Synthese und Struktur diastereomerer, zweikerniger Kupferkomplexe [1] Synthesis and Structure of Diastereomerie Dinuelear C opper Complexes [1]  
 Abstract    Depolym erisation of a copper(II)/pyrrolidine-based 2D -polym er 2 by 4.4'-bipyridyl [molar ratio: 2 (C u L 2) : l (Bipy)] and recrystallisation o f the reaction product leads to two visually distinguishable crystal charges, composed of dark green octahedra m eso-4 and light green rod-shaped crystals racem-5. Separation of the conglom erate of the morphologically different crystals is accomplished by pick out. The structure of the dinuelear complex racem-5 has been established unambigously by X-ray structure analysis. EPR and susceptibility measure­ ments of mixtures of complex meso-4 and racem-S indicate that there is no interaction be­ tween the two copper(II) centres. 
  Reference    Z. Naturforsch. 49b, 1410—1414 (1994); eingegangen am 17. März 1994 
  Published    1994 
  Keywords    Coordination Polymers, Depolymerisation, Dinuelear Copper Complexes, Diastereomers, X-Ray 
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 TEI-XML for    default:Reihe_B/49/ZNB-1994-49b-1410.pdf 
 Identifier    ZNB-1994-49b-1410 
 Volume    49