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1976 (1)
1Author    Joachim Fuchs, Soroush Mahjour, Rosemarie PalmRequires cookie*
 Title    Über Tetraalkylammonium -polyvanadate Tetraalkylammoniumpolyvanadates  
 Abstract    In the reaction of V2O5 with aqueous or alcoholic solutions of tetraalkylammonium-hydroxide the orange decavanadates (NR4)3H3Vio028; (NR4)4H2VIO028> (NR4)5HVio028, (NR4)6VLO028 and colourless metavanadates can be obtained. The tetrabutylammonium-salt [N(C4H9)4]3HV40i2 is the first known metavanadate with discrete polyanion. Its molecular weight was determined by vapor pressure osmometry in chloroform. The Raman spectrum is identical with the spectrum of a sodium metavanadate solution. The vibration spectra of the compounds are discussed and partial assignments were made. Dekavanadate der Zusammensetzung (NR4)3H3VIO028 und (NR4)2H4VI0O28 
  Reference    (Z. Naturforsch. 31b, 544—548 [1976]; eingegangen am 12. Januar ' 20. Februar 1976) 
  Published    1976 
  Keywords    Decavanadates, Metavanadate, Discrete Polyanion, Preparation, Vibration Spectra 
  Similar Items    Find
 TEI-XML for    default:Reihe_B/31/ZNB-1976-31b-0544.pdf 
 Identifier    ZNB-1976-31b-0544 
 Volume    31