Go toArchive
Browse byFacets
Bookbag ( 0 )
'D iiodo' in keywords Facet   Publication Year 1996  [X]
Results  1 Item
Sorted by   
Section
Publication Year
1996[X]
1Author    PaulK. Baker3, DavidJ M Uldoona, MichaelB. Hursthouseb, SimonJ. Colesb, AidanJ. Laveryc, Andrew ShawcrosscRequires cookie*
 Title    The Crystal Structure and Low Temperature 13C NMR Spectrum of the Seven-Coordinate Complex of Tungsten(II), [WI2(CO)3(NCPh)2]  
 Abstract    The crystal structure of [WI2(C O)3(N C Ph)2] (1) has been determined by X-ray methods. The crystals are orthorhombic, space group Pnam, a = 7.815(3), b = 13.839(5), c = 18.475(3) Ä, Z = 8, R -0.0346 for 1497 observed data. The complex [WI2(C O)3(NCPh)2] has a seven-coordinate geometry, which may be described as a distorted capped octahedron, with the two iodo-ligands mutually trans, while each nitrile is trans to a carbonyl group. The capped octahedral geometry consists of a capping carbonyl (C(10)} on the face defined by 1(1), C(20) and C(20)#. However, the geom etry may also be described as a capped trigonal prism, which has one triangular face occupied by three carbonyl groups and the second triangular face occupied by N (l) , N (l)# and 1(1) atoms, respectively. The iodide 1(2) occupies the capping position on the rectangular face defined by the atoms C(20), C(20)#, N (l), and N (l)# . The low temperature 13C NM R spectrum (203 K, C D 2C12) of 1 shows a single carbonyl resonance at 219.27 ppm which indicates that the com plex is undergoing a rapid fluxional process in solution at 203 K. 
  Reference    Z. Naturforsch. 51b, 263 (1996); received July 7 1995 
  Published    1996 
  Keywords    Crystal Structure, Benzonitrile, Carbonyl, D iiodo, Tungsten(II) 
  Similar Items    Find
 DEBUG INFO      
 TEI-XML for    default:Reihe_B/51/ZNB-1996-51b-0263.pdf 
 Identifier    ZNB-1996-51b-0263 
 Volume    51