| 1 | Author | G. Ottfried Pawelke, Ralph Dammei, Wolfgang Poll | Requires cookie* |
| Title | Darstellung von Difluormethanimin F2C = N H und F2C = N D durch Hydrolyse von CF3NCO Preparation of Difluoromethanimine F 2C = NH and F 2C = ND by Hydrolyses of C F 3NCO  | ||
| Abstract | The title com pounds have been prepared by controlled hydrolysis o f C F 3NCO in N E t3. Their 13C, 19F and 'H N M R spectra are reported and their IR gas and IR matrix spectra are discussed in terms o f a normal coordinate analysis. The photoelectron spectrum o f F2C = NH is compared with those o f F2C = N F and H 2C = N H revealing a strong fluoro effect. In the solid state F2C = N H is aggregated to infinite zig-zag chains by N • • • H hydrogen bonding. | ||
| Reference | Z. Naturforsch. 47b, 351 (1992); eingegangen am 17. September 1991 | ||
| Published | 1992 | ||
| Keywords | D ifluoromethanimine, N M R Spectra, Vibrational Spectra, Photoelectron Spectra, X-Ray | ||
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