| | 1 | Author
| Peer Berges, Volker Mansei, G. Ünter Klar | Requires cookie* | | | Title
| Elementorganische Verbindungen mit ö-Phenylenresten, XXIII [1]  | | | | Abstract
| 2.3.6.9.10.13-Hexam ethoxy-5,7,12,14-tetrathia-5,7,12,14-tetrahydropentacen -2.3-Dichlor-5,6-dicyan-l,4-benzochinon (1/2) Organometalloidal Com pounds with o-Phenylene Substituents, XXIII [1] 2.3.6.9.10.13-Hexamethoxy-5,7,12,14-tetrathia-5,7,12,14-tetrahydropentacene -2.3-Dichloro-5,6-dicyano-1,4-benzoquinone (1 /2) The title com pound is prepared by com bining hot solutions o f the components. X-ray anal ysis shows hexam ethoxytetrathiatetrahydropentacene to act as a bifunctional donor, each o f its dimethoxybis(organylthio)benzene units being in contact with a dichlorodicyanoquinone molecule. In the crystal stacks o f the type D A 2 ,D A 2, with an alternating arrangement o f d o nor and acceptor molecules are formed. In the com plex the donor has a m -conform ation (boat form) in contrast to its pure form where the /ra/w-conformation (chair form) is found. | | | |
Reference
| Z. Naturforsch. 47b, 211 (1992); eingegangen am 26. August 1991 | | | |
Published
| 1992 | | | |
Keywords
| Hexamethoxytetrathiatetrahydropentacene, Bifunctional D onor, D ichlorodicyanoquinone, Crystal Structure, X-Ray | | | |
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| default:Reihe_B/47/ZNB-1992-47b-0211.pdf | | | | Identifier
| ZNB-1992-47b-0211 | | | | Volume
| 47 | |
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