1 | Author | D. Ietm Ar Kuck | Requires cookie* |
Title | Synthesis of Regio-and Stereospecifically Deuterium Labelled 2-Benzylindanes ![]() | ||
Abstract | 1, la) are hydrogenated to 2-benzylindanes (2) using tris-(triphenylphos-phine)-rhodium (I)-chloride in benzene by a strict cis-1,2 addition of hydrogen to the double bond. Thus, stereo-and regio-specific deuterium labelling at the five-membered ring of various 2-benzylindanes has been carried out. The high selectivity of deuterium incorporation is shown independently by 'H N M R and mass (M IK E*) spectrometry of selected 2-benzylindanes. | ||
Reference | Z. Naturforsch. 39b, 369—374 (1984); received Septem ber 19 1983 | ||
Published | 1984 | ||
Keywords | Indanes, Indenes, D euterium Labelling, H om ogeneous Catalytic Hydrogenation, Stereochemistry 2-Benzylindenes ( | ||
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