| | 1 | Author
| Stephan Von, B. Eckeratha, Ingo-Peter Lorenz, Riad Fawzib, M. Anfred, Steim Annb | Requires cookie* | | | Title
| C  | | | | Abstract
| p(C O)2M nN (Bz)C H 2CH2 , der erste einzähnig koordinierte A ziridin-K om plex C p(C O)2M nN (B z)C H 2C H 2, the First M ono-C oordinate A ziridine Com plex The photolytically induced CO-substitution reaction of CpM n(CO b with N-benzyl-aziridine leads to the first mono coordinate aziridine complex, Cp(CO)2MnN(Bz)CH2CH2. It is stable against thermal C2H4 elimination up to 135°C. No nitrene complexes {Cp(CO)2Mn}"NBz (/? = 1, 2) were detected. The X-ray structure analysis of Cp(CO)2MnN(Bz)CH2CH2 shows the intact three-membered ring ligand and the pyramidal configuration of the nitrogen atom. | | | |
Reference
| Z. Naturforsch. 51b, 959—962 (1996); eingegangen am 12. Januar 1996 | | | |
Published
| 1996 | | | |
Keywords
| N-Benzyl-aziridine, Substitution, Cymantrene, X-Ray | | | |
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| default:Reihe_B/51/ZNB-1996-51b-0959.pdf | | | | Identifier
| ZNB-1996-51b-0959 | | | | Volume
| 51 | |
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