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'Cymantrene' in keywords Facet   section ZfN Section B:Volume 051  [X]
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1996 (1)
1Author    Stephan Von, B. Eckeratha, Ingo-Peter Lorenz, Riad Fawzib, M. Anfred, Steim AnnbRequires cookie*
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 Abstract    p(C O)2M nN (Bz)C H 2CH2 , der erste einzähnig koordinierte A ziridin-K om plex C p(C O)2M nN (B z)C H 2C H 2, the First M ono-C oordinate A ziridine Com plex The photolytically induced CO-substitution reaction of CpM n(CO b with N-benzyl-aziridine leads to the first mono coordinate aziridine complex, Cp(CO)2MnN(Bz)CH2CH2. It is stable against thermal C2H4 elimination up to 135°C. No nitrene complexes {Cp(CO)2Mn}"NBz (/? = 1, 2) were detected. The X-ray structure analysis of Cp(CO)2MnN(Bz)CH2CH2 shows the intact three-membered ring ligand and the pyramidal configuration of the nitrogen atom. 
  Reference    Z. Naturforsch. 51b, 959—962 (1996); eingegangen am 12. Januar 1996 
  Published    1996 
  Keywords    N-Benzyl-aziridine, Substitution, Cymantrene, X-Ray 
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 TEI-XML for    default:Reihe_B/51/ZNB-1996-51b-0959.pdf 
 Identifier    ZNB-1996-51b-0959 
 Volume    51