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'Cyclosilazanes' in keywords Facet   Publication Year 1987  [X]
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1987[X]
1Author    Ernst Egert, Ursula Kliebisch, Uwe Klingebiel, Dieter SchmidtRequires cookie*
 Title    Cyclodi-und -trisilazane — Synthese, Reaktionen und Ringkopplungen Cyclodi-and -trisilazanes — Synthesis, Reactions and Ring Coupling  
 Abstract    Contrary to our expectations, a cyclotrisilazane is obtained instead of a cyclodisilazane by the reaction of the lithiated di-rerf-butyldiamino-silane with Hal 2 SiMe 2 . Mono-and disubstitution takes place in reactions of lithiated tetra-isopropyl cyclodisilazane with halogeno-silanes and -boranes. A disubstituted ring reacts with LiOC 4 H 9 -formed from LiC 4 H y and THF — to give an unsymmetrically substituted four-membered ring as proved by a crystal structure determination. Coupling of four-and six-membered rings occurs in the reaction of SiF-substituted and lithiated rings. 
  Reference    (Z. Naturforsch. 42b, 23—30 [1987]; eingegangen am 1. September 1986) 
  Published    1987 
  Keywords    Cyclosilazanes, Substitution, Ring Coupling, Crystal Structure 
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 TEI-XML for    default:Reihe_B/42/ZNB-1987-42b-0023.pdf 
 Identifier    ZNB-1987-42b-0023 
 Volume    42