| | 1 | Author
| Ralf Steudel, Jürgen Steidel, Torsten Sandow, Fritz Schuster | Requires cookie* | | | Title
| Convenient Preparation and Vibrational Spectra of Cyclodecasulfur, S10, and of the Adduct S6 * S10 [1]  | | | | Abstract
| Thermal decomposition of S6O2 and S7O, respectively, in CH2CI2 or CS2 solution at temperatures between 20 and 5 °C yields SO2, polymeric sulfur and S10 which was obtained as pure single crystals in yields of 7-11% with regard to the starting materials S6 and S7, respectively. Infrared and Raman spectra of S10 as well as of the new molecular addition compound Se • S10 are reported. S10 is one of the thermodynamically instable ätiotropes of sulfur and originally was prepared according to: 2 (C5H5)2TIS5 + 2 SO2CI2 S10 + 2 S02 + 2 (C5H5)2TiCl2 | | | |
Reference
| Z. Naturforsch. 33b, 1198—1200 (1978); eingegangen am 6. Juli 1978 | | | |
Published
| 1978 | | | |
Keywords
| Cyclodecasulfur, Preparation, Vibrational Spectra, Cycloheptasulfur Oxide, Cyclohexasulfur Dioxide | | | |
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| default:Reihe_B/33/ZNB-1978-33b-1198_n.pdf | | | | Identifier
| ZNB-1978-33b-1198_n | | | | Volume
| 33 | |
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