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1978 (1)
1Author    HerbertW. Roesky, Klaus AmbrosiusRequires cookie*
 Title    Über Reaktionen von 3-trifluormethylphenylsubstituierten silicium-und zinnorganischen Verbindungen Reactions of 3-Trifluoromethylphenyl Substituted Silicon and Tin Organic Compounds  
 Abstract    Several routes were investigated for the preparation of 3-CF3C6H4N[Si(CH3)3]2 2 and 3-CF3C6H4N[Sn(CH3)3]2 3. The latter compound reacts with 3-CF3C6H4NCO to yield [3-CF3C6H4(CH3)3SnN]2CO 4. A substituted urea 5 is also formed from [(CH3)3Si]2NCH3 and 3-CF3C6H4NCO. 5 is used for the preparation of cyclic compounds, with S2CI2 the ten-membered ring (3-CF3C6H4NCONCH3S2)2 6 is formed. 5 and HN(S02C1)2 yield the six-membered ring 3-CF3C6H4NC0NCH3(S02)2NH 7. SeOCl2 and 5 react under formation of a spiro compound (S-CFsCeHjNCONCHs^Se 8. The compounds were characterized on the basis of mass and 19 F NMR spectra. Am Beispiel des CF3S02N[Sn(CH3)3]2 und seiner 
  Reference    Z. Naturforsch. 33b, 759—762 (1978); eingegangen am 24. April 1978 
  Published    1978 
  Keywords    Fluoro Compounds, Cycles, Silicon, Tin, Metal Organic Derivatives 
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 TEI-XML for    default:Reihe_B/33/ZNB-1978-33b-0759.pdf 
 Identifier    ZNB-1978-33b-0759 
 Volume    33