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1998 (1)
1Author    Horst Kunkely, Arad VoglerRequires cookie*
 Title    Photooxidation of Dicyanoaurate(I) Induced by Metal-to-Ligand Charge Transfer Excitation  
 Abstract    The irradiation of [Au(CN)2]_ in oxygen-saturated acetonitrile leads to photooxidation of Au(I). In the presence of additional chloride [AutCN^CL]-is formed with < /> = 0 .5 x 1 0 -4 at Ajrr = 2 5 4 nm. It is assumed that [Au(CN)2]~ in its metal-to-ligand charge transfer state undergoes an excited state electron transfer to oxygen in the primary photochemical step. 
  Reference    Z. Naturforsch. 53b, 853—855 (1998); received April 12 1998 
  Published    1998 
  Keywords    Photochemistry, Charge Transfer, Gold Complexes, Cyanide Complexes 
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 TEI-XML for    default:Reihe_B/53/ZNB-1998-53b-0853.pdf 
 Identifier    ZNB-1998-53b-0853 
 Volume    53