Go toArchive
Browse byFacets
Bookbag ( 0 )
'Cubane Like Cage' in keywords Facet   section ZfN Section B  [X]
Results  1 Item
Sorted by   
Publication Year
1981 (1)
1Author    M. Veith, 0. RecktenwaldRequires cookie*
 Title    Cyclische Diazastannylene, X [1] Die Kristall-und Molekülstruktur eines Moleküls mit verzerrt-würfelförmigem Sn4N30-Käfig Cyclic Diazastannylenes, X [1] The Crystal and Molecular Structure of a Molecule with a Distorted Cube-Shaped SiLiNsO-Cage  
 Abstract    The crystal and molecular structure of (me3CN)3(me3A10)Sn4 has been determined from three-dimensional X-ray data (4-circle diffractometer, R — 0.048). The crystals are mono-clinic, space group P2i/c, with cell dimensions a = 1017.4(5), b — 1488.5(7), c = 1748(1) pm, jS—91.5(1)° and Z — 4. The molecules approach 3m point-symmetry and include a SruNsO-cage, the atoms occupying the corners of a distorted cube formed by two, differently sized, interpenetrating concentric tetrahedra of tin and nitrogen/oxygen atoms. The nitrogen atoms are attached to tert-butyl groups, whereas the oxygen atom of the cage acts as a base towards the aluminiumtrimethyl group. Typical bond distances and angles (mean values) are: Sn-N = 219.9, Sn-0 = 220.3 pm; N-Sn-N = 81.2°; N-Sn-0 = 79.0°; Sn-N-Sn = 98.8° and Sn-O-Sn -100.2°. 
  Reference    Z. Naturforsch. 36b, 144—149 (1981); eingegangen am 14. Oktober 1980 
  Published    1981 
  Keywords    Molecular Tin(II) Compounds, Iminostannylenes, Cubane-Like Cage, X-ray, Molecular Structure 
  Similar Items    Find
 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-0144.pdf 
 Identifier    ZNB-1981-36b-0144 
 Volume    36