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281	Author		Requires cookie*
	Title	Röntgenographische Strukturuntersuchung von Cäsiumhexaoxo-tetrahydroxo-pentaborat-2-dimethylsulfoxid X-ray Study of the Structure of Cesiumhexaoxo-tetrahydroxo-pentaborate-2-dimethyl Sulfoxide
	Abstract	The compound Cs[Bs0 6 (OH)4 ] • 2 DMSO was prepared by hydrolysis of tris(methoxy)-borane in organic solvents with small amounts of water in presence of cesium ierf-butylate and recrystallized in DMSO (dimethyl sulfoxide). Cs[Bs0 6 (0 H)4 ] • 2 DMSO crystallizes in the monoclinic space group P2i/a with a = 9.593(2), 6 = 19.179(4), c = 11.585(2) Ä, ß = 119.99(2)° and Z — 4. The crystal structure was determined by single-crystal diffracto meter data and refined to a conventional R value of 9.9%. The crystal structure consists of chains of pentaborate anions [Bs0 6 (OH)4 ]-linked by hydrogen bonds. The cesium cation and the DMSO molecules join the chains to sheets by coordination and hydrogen bonds respectively.
	Reference	(Z. Naturforsch. 32b, 268—274 [1977]; eingegangen am 4. November/7. Dezember 1976)
	Published	1977
	Keywords	X-ray, Crystal Structure, Isopolyanions, Polyborates
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	TEI-XML for	default:Reihe_B/32/ZNB-1977-32b-0268.pdf
	Identifier	ZNB-1977-32b-0268
	Volume	32

282	Author	W.	Requires cookie*
	Title	Preparation and Crystal Structure of Li2Sb
	Reference	(Z. Naturforsch. 32b, 357—359 [1977]; eingegangen am 3. Dezember 1976)
	Published	1977
	Keywords	Lithium Antimonide, Intermetallic Compound, Crystal Structure
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	Identifier	ZNB-1977-32b-0357_n
	Volume	32

283	Author		Requires cookie*
	Title
	Abstract	G e r h a r d C o r d i e r u n d H e r b e r t S c h ä f e r BaMnSb2, SrMnBi2 and BaMnBi2 have been prepared and structurally characterized. The new compounds are isotypic and crystallize tetragonal in the SrZnBi2 structure with the following constants: BaMnSb2: a = 4.53 ± 0.01 A, c = 24.34 ± 0.03 A, c/a = 5.37. SrMnBi2: a = 4.58 ± 0.01 A , c = 23.13 ± 0.03 A, c/a = 5.05. BaMnBi2: a — 4.63 ± 0.02 A, c = 24.22 i 0.05 A, c/a = 5.23. The transition metal atoms form together with the semimetal atoms sheets of tetragonal pyramids separated by double layers of alkali earth atoms. In these double layers there are inserted Bi/Sb-square nets.
	Reference	(Z. Naturforsch. 32b, 383—386 [1977]; eingegangen am 29. Dezember 1976)
	Published	1977
	Keywords	Intermetallic Compounds, Crystal Structure, Ternary Antimonides, Ternary Bismutides
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	TEI-XML for	default:Reihe_B/32/ZNB-1977-32b-0383.pdf
	Identifier	ZNB-1977-32b-0383
	Volume	32

284	Author	W. Muschick, Hk Müller-Buschbaum	Requires cookie*
	Title	Ein Beitrag zur Kristallchemie dreiwertiger Seltenerdoxide Zur Stabilisierung der m onoklinen B-Form
	Abstract	Single crystals of 1 — a'Ho203 : xCaO (x = 0.07), CaHoC>2.5 (A) and Cao.5H 01.5O2.75 (B) were prepared by high temperature reaction and investigated with X-ray single crystal data. It can be shown that small amounts of CaO stabilize the monoclinic B-Typ of rare earth oxides. Phase (A) and (B) cannot be seen as a stabilized B-type crystal because they have an new crystal structure with space group C.7h-P 2 i/m, a = 656.6, b = 356.7, c = 529.4pm , ß = 92.3°; a = 650.2, b = 352.4, c = 584.5, ß = 92.3°.
	Reference	(Z. Naturforsch. 32b, 495—498 [1977]; eingegangen am 15. Februar 1977)
	Published	1977
	Keywords	Holmium, Thulium, Calcium, X-ray, Crystal Structure
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	TEI-XML for	default:Reihe_B/32/ZNB-1977-32b-0495.pdf
	Identifier	ZNB-1977-32b-0495
	Volume	32

285	Author		Requires cookie*
	Title	Über die Tricyanatomercurate KHg(NCO)3 und RbHg(NCO)3 - Synthesen, Kristallstrukturen und Schwingungsspektren
	Abstract	On th e Cyanatom ercurates K H g(N C O)3 and R bH g(N C O)3 -Syntheses, Crystal Structures and V ibrational Spectra G e r h a r d T h i e l e u n d P e t e r H i l f r i c h B y m ixing aqueous solutions of Hg(CH3COO)2 and KOCN the white precipitate K 2 Hg3(NCO)8 is formed. When recrystallised from CH3OH colorless crystals of the compound KHg(NCO)3 are obtained. The crystal structure analysis (space group Pnma; a — 1015.2(6) pm, b = 399.3(3) pm, c = 1772.9(9) pm) shows a distorted KCdCl3 arrange ment w ith isolated Hg(NCO)2 molecules, K+ and NCO~ ions. The vibrational spectra in the range of 250-3000 cm-1 are discussed. The rubidium compound is isotypous (a = 1019.0(6) pm, b = 411.6(4) pm, c = 1820.5(8) pm).
	Reference	(Z. Naturforsch. 32b, 1239—1243 [1977]; eingegangen am 25. Juli 1977)
	Published	1977
	Keywords	Cyanatomercurate, Cyanato Complex, Crystal Structure, Vibrational Spectra
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	TEI-XML for	default:Reihe_B/32/ZNB-1977-32b-1239.pdf
	Identifier	ZNB-1977-32b-1239
	Volume	32

286	Author	W. Alter, J. Ung	Requires cookie*
	Title	Preparation and Crystal Structure of MgNi2,sB2 and Li1.2Ni2.5B2
	Reference	(Z. Naturforsch. 32b, 1371—1374 [1977]; eingegangen am 5. A ugust 1977)
	Published	1977
	Keywords	Magnesium Nickel Boride, Lithium Nickel Boride, Crystal Structure
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	TEI-XML for	default:Reihe_B/32/ZNB-1977-32b-1371.pdf
	Identifier	ZNB-1977-32b-1371
	Volume	32

287	Author	Cyclic Diazastannylenes, Iii, M. Veith	Requires cookie*
	Title	Cyclische Diazastannylene, DI 1 Die Kristall-und Molekülstruktur der monoklinen Phase von 1.3-Di-feri-butyl-2.2-dimethyl-1.3.2.4A 2 -diazasilastannetidin The Crystal and Molecular Structure of the Monoclinic Phase of l,3-Di-feri-butyl-2,2-dimethyl-l,3,2,4A 2 -diazasilastannetidine
	Abstract	The crystal and molecular structure of the monoclinic phase of l,3-di-£eri-butyl-2,2-dimethyl-l,3,2,4A 2 -diazasilastannetidine has been determined from three-dimensional X-ray data collected on a two-circle diffractometer at —120 °C (MoKa radiation, 2623 re-flexions, R — 0,050). The crystals are monoclinic, space group C 2/c, with cell dimensions a = 10.655(5), b = 25.75(1), c = 17.33(1) A, ß = 106.8(1)° and Z = 12. Four monomeric (crystal site symmetry 2 (C2)) and four dimeric units (crystal site symmetry I (Cj)) are present in the structure interacting over tin-tin (3.68 A). Remarkable are the very short Sn-N bond (2.09 A) in the monomer and the donation bond Sn-N (2.39 Ä) in the dimer. The coordination of the tin atoms in the different units is discussed in detail.
	Reference	(Z. Naturforsch. 33b, 7—13 [1978]; eingegangen am 5. September/6. Oktober 1977)
	Published	1978
	Keywords	Diazastannylenes, X-ray, Molecular Structure, Crystal Structure
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	TEI-XML for	default:Reihe_B/33/ZNB-1978-33b-0007.pdf
	Identifier	ZNB-1978-33b-0007
	Volume	33

288	Author	Hk Müller-Buschbaum, M. Harder	Requires cookie*
	Title	Zur Kenntnis von Ba2Fe2 Fe9 3 Aln034 About Ba2Fe2 2+ Fe9 3+ Alii034
	Abstract	Single crystals of the compound Ba2FenAln034 were prepared by solid state reac-tion (1700 °C) of Ba0-Fe203-Al203 mixtures. The crystal structure was investigated by X-rav data (space group D6h-P63/mmc, lattice constants: a = 565.3, c = 2281.0 pm). Ba2FenAln034 is isotypic with Na20 • 11 AI2O3, the structure of)S-alumina.
	Reference	Z. Naturforsch. 33b, 146—148 (1978); eingegangen am 8. Dezember 1977
	Published	1978
	Keywords	Barium, Iron, Aluminium, X-ray, Crystal Structure
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	TEI-XML for	default:Reihe_B/33/ZNB-1978-33b-0146.pdf
	Identifier	ZNB-1978-33b-0146
	Volume	33

289	Author	Peter Klüfers, Albrecht Mewis	Requires cookie*
	Title	Zur Struktur der Verbindungen BaZn2P2 und BaZn2As2 The Crystal Structure of BaZii2P2 and BaZn2As2
	Abstract	New yü?2-X^2-compounds, BaZn2?2 and BaZn2As2, were prepared. The structures were determined by X-ray methods. In the case of BaZn2P2 (S.G. I4/mmm; a = 4.019 A, c = 13.228 A) layers of edgeshared ZnP4-tetrahedra alternate with Ba-layers; in the case of BaZn2As2 (S.G. Pnma; a = 10.010 A, b = 4.246 A, c = 10.910 A) Zn and As build a 3D-network of edge and vertex shared tetrahedra with Ba in the holes of this network.
	Reference	Z. Naturforsch. 33b, 151—155 (1978); eingegangen am 19. Oktober 1977
	Published	1978
	Keywords	Ternary Barium Compounds, Zinc, Phosphide, Arsenide, Crystal Structure
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	TEI-XML for	default:Reihe_B/33/ZNB-1978-33b-0151.pdf
	Identifier	ZNB-1978-33b-0151
	Volume	33

290	Author	Erich Sepp, Albert Pürzer, Gerhard Thiele, Helmut Behrens	Requires cookie*
	Title	Zur Struktur des Cycloheptatrienid-tricarbonyl-eisen(0)-Anions, [C7H7Fe(CO)3] The Structure of the Cyeloheptatrienide Triearbonyl Iron(O) Anion, [C7H7Fe(CO)3]~
	Abstract	The crystal structure of the [C7H7Fe(CO)3] _ anion stabilized with the [(CeHs^As]" 1 " cation has been determinated by X-ray diffraction. The crystals are monoclinic, space group P2i/n. The unit cell with lattice constants a = 1607.9 pm, b = 1386.8 pm, c = 1249.1 pm and ß — 91.52° includes four formula units. The Fe(CO)3 group is bonded to the allyl anion part of the C7H7 ring system, while the diene part is unco-ordinated.
	Reference	Z. Naturforsch. 33b, 261—264 (1978); eingegangen am 19. Dezember 1977
	Published	1978
	Keywords	Cyeloheptatrienide Anion, Iron Carbonyl Derivate, Crystal Structure
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	TEI-XML for	default:Reihe_B/33/ZNB-1978-33b-0261.pdf
	Identifier	ZNB-1978-33b-0261
	Volume	33

291	Author	Gerhard Savelsberg, Herbert Schäfer	Requires cookie*
	Title	Ternäre Pnictide und Chalkogenide von Alkalimetallen und IB-bzw. IIB-Elementen On Ternary Pnictides and Chalkogenides of Alkaline Metals and IB-resp. II B-Elements
	Abstract	The new compounds NaCuSe, NaCuTe, KCuSe, KCuTe and KZnP were prepared and their structures -together with those of KZnSb, NaCdSb and NaZnSb -determined. NaCuSe, NaCuTe and NaZnSb crystallize in a PbFCl type, while NaCdSb forms the awta'-PbCl2-structure. KCuSe, KCuTe, KZnP and KZnSb build up the Ni2ln-structure.
	Reference	Z. Naturforsch. 33b, 370—373 (1978); eingegangen am 31. Januar 1978
	Published	1978
	Keywords	Intermetallic Compounds, Crystal Structure, Ternary Pnictides, Ternary Chalkogenides
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	TEI-XML for	default:Reihe_B/33/ZNB-1978-33b-0370.pdf
	Identifier	ZNB-1978-33b-0370
	Volume	33

292	Author	Jürgen Fenner	Requires cookie*
	Title	Die Kristallstruktur des Zinnsulfidiodids Sn4SI6 The Crystal Structure of S114SI6
	Abstract	The new ternary tin(II) sulfide iodide SnjSIß was prepared by annealing of stoichio-metric amounts of S11I2 and SnS at 280 °C. The structure of this compound was determined from three-dimensional X-ray data. The cell parameters for the monoclinic phase are a = 14.129, b = 4.425, c = 25.15Ä, and £ = 93.42°; space group C2/m (No. 12), Z = 4. Parts of the structure are built up of the Snl2 structure.
	Reference	Z. Naturforsch. 33b, 479—481 (1978); eingegangen am 6. Februar 1978
	Published	1978
	Keywords	Tin(II) Sulfide Iodide, Preparation, Crystal Structure
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	TEI-XML for	default:Reihe_B/33/ZNB-1978-33b-0479.pdf
	Identifier	ZNB-1978-33b-0479
	Volume	33

293	Author	Hans-Dieter Hausen, Herbert Binder, Wolfgang Schwarz	Requires cookie*
	Title	Die Kristallstruktur von Tetramethylstiboniumtetrachlorogallat [(CH3)4Sb] + [GaCl4]- The Crystal Structure of Tetramethylstibonium Tetrachlorogallate [(CH3)4Sb]+[GaCl4]
	Abstract	Tetramethylstiboniumtetrachlorogallate crys-tallizes in the hexagonal space group P6smc with two formula units per cell. The lattice constants are a=b = 768.8 pm and c= 1251.2 pm. The structure shows isolated cationic and anionic tetrahedra, which are only slightly distorted. The averaged bond lengths are: Sb-C 212.6 pm and Ga-Cl 217.2 pm. In good agreement with the short Ga-Cl distance (the shortest of all compounds ((CH3)nGaCl4_B)~; n = 1-3) are the measured ionization energies of Ga-3d-electrons and the calculated Pauling Qp-values.
	Reference	Z. Naturforsch. 33b, 567—569 (1978); eingegangen am 1. März 1978
	Published	1978
	Keywords	Tetramethylstibonium, Tetrachlorogallate, Crystal Structure, X-ray
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	TEI-XML for	default:Reihe_B/33/ZNB-1978-33b-0567_n.pdf
	Identifier	ZNB-1978-33b-0567_n
	Volume	33

294	Author	Klaus Volk, Wiking Müller	Requires cookie*
	Title	Li5NaSn4 -eine Phase mit gewellten Sn-Sechsecknetzen LisNaSiu -a Phase with Puckered Nets of Six-Membered Sn-Rings
	Abstract	The new compound LisNaSiu has been prepared and its crystal structure determined. It crystallizes trigonal, a = 471.0 ± 0.6 pm, c = 3172 ± 5 pm, space group R3m-C3V. Half of the Sn atoms build up a puckered net of connected six-membered rings, the other half is bound to the net atoms, forming a tetrahedral Sn-Sn coordination for these. The structural relations of this Sn sublattice to the diamond lattice are discussed. Einführung
	Reference	Z. Naturforsch. 33b, 593—596 (1978); eingegangen am 17. März 1978
	Published	1978
	Keywords	Intermetallic Compound, Alkaline Stannide, Crystal Structure
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	TEI-XML for	default:Reihe_B/33/ZNB-1978-33b-0593.pdf
	Identifier	ZNB-1978-33b-0593
	Volume	33

295	Author	Gerhard Thiele, Peter Hilfrich	Requires cookie*
	Title	Über Cyanatomercurate M2Hg3(NCO)8 (M = K, Rb, Cs) - Synthesen, Kristallstrukturen und Schwingungsspektren On Cyanatomercurates M2Hg3(NCO)8 (M = K, Rb, Cs) - Syntheses, Crystal Structures and Vibrational Spectra
	Abstract	By mixing aqueous solutions of Hg(CH3COO)2 and MOCN (M = K, Rb, Cs) the tri-clinic compounds M2Hg3(NCO)8 are formed. In a first approximation the crystal structure analysis indicates isolated Hg(NCO)2 molecules besides K+ and NCO~ ions. As in the range of van der Waals radii additional NCO-neighbours are noticed the mercury atoms are surrounded by distorted octahedra. The octahedra around 2/3 of the Hg form infinite chains as in KHg(NCO)3 which are linked together by additional Hg(NCO)2 molecules. Therefore the compound can be formulated as a double salt 2 KHg(NCO)3 • Hg(NCO)2. The vibrational spectrum is discussed. Rb2Hg3(NCO)8 is isotypous while the caesium salt has a double cell volume.
	Reference	Z. Naturforsch. 33b, 597—602 (1978); eingegangen am 20. März 1978
	Published	1978
	Keywords	Cyanatomercurate, Cyanato Complexes, Crystal Structure, Vibrational Spectra
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	TEI-XML for	default:Reihe_B/33/ZNB-1978-33b-0597.pdf
	Identifier	ZNB-1978-33b-0597
	Volume	33

296	Author	Siegfried Pohl	Requires cookie*
	Title	Cis-2-telluro-1.3.22 5 .4A 3 -diazadiphosphetidin - Kristallstruktur eines in Lösung fluktuierenden Redoxsystems Cis-2-telhirium-1.3.2/ 5 .4A 3 -diazadiphosphetidine - Crystal Structure of a Redox System Fluctuating in Solution
	Abstract	The crystal structure of the title compound was determined from single crystal X-ray data. The compound crystallises in the orthorhombic space group Pnma. In contrast to the solution where fluctuating P-Te bonds have been established by NMR analyses the crystals contain isolated molecules with fixed P-Te bonds (bond length: 235.4 pm). The four-membered phosphorus nitrogen ring exhibits significant deviations from planarity. The P-N bond lengths were found to be 168.3 and 175.0 pm, respectively.
	Reference	Z. Naturforsch. 33b, 610—613 (1978); eingegangen am 17. Februar 1978
	Published	1978
	Keywords	Crystal Structure, Four-Membered Phosphorus Nitrogen Ring, Phosphorus Tellurium Compound
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	TEI-XML for	default:Reihe_B/33/ZNB-1978-33b-0610.pdf
	Identifier	ZNB-1978-33b-0610
	Volume	33

297	Author	Klaus Deller, Brigitte Eisenmann	Requires cookie*
	Title	BaSb3, ein Antimonid mit einem zwei- dimensional unendlichen [Sb3 2 ] n-Poly anion BaSb3, an Antimonide with an Infinite Twodimensional [Sb3 2 ~]n -Anion
	Abstract	The new compound BaSb3 has been prepared and its structure determined. It crystallizes monoclinic (C 2/m, a = 1080.7(5) pm, b = 851.9(5) pm, c = 647.1(5) pm, ß = 112.66(4)°). The Sb-atoms build up 14-rings of two-and threebonded Sb, which are connected to puckered nets.
	Reference	Z. Naturforsch. 33b, 676—677 (1978); eingegangen am 17. März 1978
	Published	1978
	Keywords	Barium Antimonide, Crystal Structure, Intermetallic Compound
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	TEI-XML for	default:Reihe_B/33/ZNB-1978-33b-0676_n.pdf
	Identifier	ZNB-1978-33b-0676_n
	Volume	33

298	Author	Hk Müller-Buschbaum, K. Sander	Requires cookie*
	Title	Zur Kristallstruktur von Sr6(Cr04)3Cl On the Crystal Structure of Sr5(Cr04)3Cl
	Abstract	Single crystal X-ray investigation shows that Sr5(Cr04)3Cl is not isotypic with the apatite structure as being affirmed up to now. Chlorine occupies a position other than z = 0.250 implying the lower symmetry Cg-P63. As a consequence one strontium coordination sphere changes from octahedral to trigonal prismatic.
	Reference	Z. Naturforsch. 33b, 708—710 (1978); eingegangen am 12. April 1978
	Published	1978
	Keywords	Chlorine, Chromium, Oxygen, Strontium, Crystal Structure
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	TEI-XML for	default:Reihe_B/33/ZNB-1978-33b-0708.pdf
	Identifier	ZNB-1978-33b-0708
	Volume	33

299	Author	Gerhard Savelsberg, Herbert Schäfer	Requires cookie*
	Title	Darstellung und Kristallstruktur von Na2 AgAs und KCuS Preparation and Crystal Structure of Na2AgAs and KCuS
	Abstract	The title compounds have been prepared and their structures determined. Na2AgAs crystallizes in the Na2CuAs structure type, forming infinite Ag-As-zig-zag-chains. KCuS builds up a new structure type but with similar zig-zag-chains of Cu-and S-atoms. Crystallographic data:
	Reference	Z. Naturforsch. 33b, 711—713 (1978); eingegangen am 3. April 1978
	Published	1978
	Keywords	Ternary Pnictides, Ternary Chalcogenides, Crystal Structure
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	TEI-XML for	default:Reihe_B/33/ZNB-1978-33b-0711.pdf
	Identifier	ZNB-1978-33b-0711
	Volume	33

300	Author	T.Stanley Cameron, RuthE. Cordes, FlorenceA. Jackman	Requires cookie*
	Title	Synthesis and Crystal Structure of iu-Oxo-bis(phosphenyl-or^o-toluidide)
	Abstract	The title compound was synthesised in an attempt to prepare phosphenyl-tri-orJ/io-toluidine, X-ray crystallographic studies show that it contains a P-O-P bridge with extensively hydrogen bonding between -^P=0 and H-N < groups. The P-N bond lengths are different and this can be attributed to some combination of hydrogen bonding and varying p Z7-d Z7 interactions along the bond.
	Reference	Z. Naturforsch. 33b, 728—730 (1978); received April 21 1978
	Published	1978
	Keywords	X-ray, Crystal Structure, Phosphorus-Nitrogen Bond Lengths
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	TEI-XML for	default:Reihe_B/33/ZNB-1978-33b-0728.pdf
	Identifier	ZNB-1978-33b-0728
	Volume	33

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