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61Author    H., M. Üller-Buschbaum, L. WalzRequires cookie*
 Title    Einkristallröntgenstrukturanalyse an Quecksilberchromat(VI)  
 Abstract    g 3 0 2 C r 0 4 Single C rystal X -Ray S tructure D eterm ination of a M ercury C hrom ate(V I): H g30 2C r 0 4 Th. H an sen , H k. Single crystals of Hg3C r0 6 have been prepared by high pressure techniques (3600 bar oxygen, 600 °C). Hg3C r06 crystallizes with trigonal symmetry, space group D |-P 3 212, a = 7.137(1), c = 10.017(2)Ä, Z -3. Nearly linear O -H g -O dumb-bells are connected in planes, forming strongly puckered nets of six-membered rings. Each Hg60 6 ring is centered by a C r04 tetrahedron; the C r04 tetrahedra are arranged in two equally occupied split positions. 
  Reference    (Z. Naturforsch. 50b, 47—5 [1995]; eingegangen am 2. August 1994) 
  Published    1995 
  Keywords    Mercury, Chromium, Oxide, Crystal Structure 
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 Identifier    ZNB-1995-50b-0047 
 Volume    50 
62Author    E. Peters, Hk Müller-BuschbaumRequires cookie*
 Title    Ein Titan-Tantaloxid mit Ti11: Ti0 ,3 3 Ta0 ,6 7O2 (TiTa20 6)  
 Abstract    Black single crystals o f Tio^Tao 670 2 have been prepared by C 0 2-LA SER techniques heating a mixture of TiO and Ta20 5 to T > 2000 °C. The titanium tantalum oxide crystallizes with tetragonaj symmetry, space group D 4 h -P 4 2/mnm, lattice constants a = 4.7344(6) A, c = 3.0504(2) A , Z = 2. Ti().33Ta0.67O 2 represents the compound TiTa20 6 with rutile structure because of the statistical distribution of Ti2+ and Ta5+. The composition of rutile-type com ­ pounds is discussed in more general terms. 
  Reference    Z. Naturforsch. 50b, 1167—1170 (1995); eingegangen am 16. Januar 1995 
  Published    1995 
  Keywords    Titanium, Tantalum, Oxide, Crystal Structure 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-1167.pdf 
 Identifier    ZNB-1995-50b-1167 
 Volume    50 
63Author    V. Ikto, R. Keimes, A. Lb Rech, M. EwisRequires cookie*
 Title    M g6N i16A s7 -a N ew G Phase  
 Abstract    Mg6N i16A s7 (F m 3m ; a = 11.479(1) Ä; Z = 4) was prepared by heating a mixture of the ele ­ ments and investigated by m eans of single crystal X-ray methods. The arsenide crystallizes in a m o­ dified Th6Mn23 type structure, similar to many ternary com pounds of the com position A 6M 16X 7, called G phases. 
  Reference    Z. Naturforsch. 50b, 1275—1276 (1995); eingegangen am 6. März 1995 
  Published    1995 
  Keywords    Ternary Nickelarsenide, Magnesium, Crystal Structure 
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 Identifier    ZNB-1995-50b-1275_n 
 Volume    50 
64Author    T. Gressling, Hk Müller-BuschbaumRequires cookie*
 Title    Zur Kristallstruktur von Ce2(W 0 4)3 On the Crystal Structure of Ce2(W 0 4)3  
 Abstract    Single crystals of Ce2(W 0 4)3 have been prepared by crystallisation from molten mixtures of W 0 3 and C e 0 2. The compound shows m onoclinic symmetry, a = 7.813(4), b = 11.720(2), c = 11.586(3), ß = 109.36(3)°, Z = 4, and is isotypic to Eu2(W 0 4)3, but shows large differences of the atomic coordinates especially of oxygen. The crystal structure of Ce2(W 0 4)3 is charac­ terized by W (1)0 4 tetrahedra, square W (2)0 5 pyramids and a distorted capped trigonal prism of oxygen around cerium. The decrease o f the oxidation states of C e4+ or W6+ was proved by thermogravimetric and magnetic measurements as well as by calculations of the Coulomb terms of lattice energy. 
  Reference    Z. Naturforsch. 50b, 1513—1516 (1995); eingegangen am 25. Mai 1995 
  Published    1995 
  Keywords    Cerium, Tungsten, Oxygen, Crystal Structure 
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 Identifier    ZNB-1995-50b-1513 
 Volume    50 
65Author    Karl Peters3, Eva-Maria Peters3, Gerhard Bringmannb, Sven HarmsenbRequires cookie*
 Title    l,4-Dibromonaphthalene-2,3-diyI- bis(l'-bromo-2'-naphthoate) * CHC13, a Potential Precursor to Lactone-Bridged Teraryls  
 Abstract    The title compound was prepared from 1,4-di-bromo-2,3-dihydroxynaphthalene by two-fold es-terification with l-bromo-2-naphthoic acid. It crystallizes from chloroform in the triclinic sys­ 
  Reference    Z. Naturforsch. 51b, 144—146 (1996); received June 20 1995 
  Published    1996 
  Keywords    Crystal Structure, Biaryl Coupling, Teraryls 
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 Identifier    ZNB-1996-51b-0144_n 
 Volume    51 
66Author    D. Frerichs, C. H. Park, Hk Müller-BuschbaumRequires cookie*
 Title    Zur Kenntnis der Tief-und Hochtemperaturform eines Oxidarsenats des Zinks: Zn0Z n3(A s0 4)2 On the Low and High Temperature Form o f an Oxidearsenate of Zinc: Z n 0 Z n 3( A s 0 4)2  
 Abstract    Single crystals of the low (t-) and high (h-) temperature form o f Z n 0 Z n 3(A s 0 4)2 have been prepared by flux and by C 0 2-L A SER techniques respectively. Both compounds crystal­ lizes monoclinic, space group C2h-P2;/n with the lattice parameters t-Z n 0 Z n 3(A s 0 4)2: a = 9.807(3), b = 8.180(2), c = 9.967(2) A , ß = 116.53(2)°, Z = 4 and h -Z n 0 Z n 3(A s 0 4)2: a = 9.743(3), b = 8.163(8), c = 17.933(2) A , ß = 91.55(2)°, Z = 8. Similarities and differences of the crystal structures will be discussed. 
  Reference    Z. Naturforsch. 51b, 233 (1996); eingegangen am 10. Juli 1995 
  Published    1996 
  Keywords    Zinc, Arsenic, Oxide, Crystal Structure 
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 Identifier    ZNB-1996-51b-0233 
 Volume    51 
67Author    Silke Busche, K. Arsten BluhmRequires cookie*
 Title    Synthese und Kristallstruktur von Dibariumzink-bis(cyclotriborat) Ba2Zn(B30 6)2  
 Abstract    Single crystals of the new compound Ba2Zn(B30 6)2 were obtained by using a B20 3 flux technique. They crystallize in an as yet unknown structure type. X-ray investigations led to space group Cj'-Pl (Nr.2) with lattice parameters a = 715.5(2), b = 720.5(2), c = 1178.9(4), a = 78.96(2)°, /3 = 85.45(2)°, j = 60.12(1)°, Z = 2. The structure is characterized by iso­ lated (B30 6)3_-rings and contains two ninefold coordinated Ba-sites. Zn2+ is tetrahedrally coordinated by oxygen. The relation to the crystal structures of high-temperature BaB20 4 and Ba2Ca(B30 6)2 is discussed. 
  Reference    Z. Naturforsch. 51b, 309—312 (1996); eingegangen am 26. September 1995 
  Published    1996 
  Keywords    Barium, Zinc, Borate, Crystal Structure 
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 Identifier    ZNB-1996-51b-0309 
 Volume    51 
68Author    D. Frerichs, C. H. Park, HkM. Üller-B, UschbaumRequires cookie*
 Title    Zur Kenntnis zweier Formen des Zinkorthoarsenates: a-Z n 3(A s04)2 und /3-Zn3(A s0 4)2 On Two Forms o f Zinc O rthoarsenate: a -Z n 3(A s 0 4)2 and /3-Zn3(A s 0 4)2  
 Abstract    Single crystals of two forms of zinc orthoarsenate (a-Z n3(A s04)2 (I) and /3-Zn3(A s04)2 (II)) have been prepared by flux techniques. Both compounds crystallize monoclinically, space groups (I): Cih-P2l/c, (II): Cih-P21/n, with the lattice parameters (I): a = 6.306(2), b = 8.652(2), c = 'ol 1.321(4) A, ß = 92.25(5) °, Z = 4 and (II): a = 5.281(1), b = 8.494(2), c = 7.726(3) A, ß = 96.39(3)°, Z = 2. ct-Zn3(A s04)2 is isotypic to I-Cu3(A s04)2 and ß-Zn3(A s04)2 to 7-Zn3(P 0 4)2. Similarities and differences of the crystal structures are discussed. 
  Reference    Z. Naturforsch. 51b, 333—337 (1996); eingegangen am 31. August 1995 
  Published    1996 
  Keywords    Zinc, Arsenic, Oxide, Crystal Structure 
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 Identifier    ZNB-1996-51b-0333 
 Volume    51 
69Author    Karl Peters3, Eva-M Aria Peters3, G.Erhard Bringmannb, O. La, F. SchuppbRequires cookie*
 Title    l,3-Dimethoxy-677- benzo[b]naphtho[l,2-d]pyran-6-thione, a Thionolactone-Bridged Axially Prostereogenic Biaryl  
 Abstract    The title compound was prepared from the cor­ responding " ordinary" oxolactone bridged biaryl using Lawesson's reagent. It crystallizes from di-chloromethane / petroleum ether in the mono­ clinic system, space group P2xla; a = 1115.7(2), 
  Reference    Z. Naturforsch. 51b, 431—432 (1996); received September 9 1995 
  Published    1996 
  Keywords    Crystal Structure, Stereochemistry, Biaryl Coupling 
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 Identifier    ZNB-1996-51b-0431_n 
 Volume    51 
70Author    J. Feldmann, Hk Müller-BuschbaumRequires cookie*
 Title    Kristallstrukturuntersuchung am Barium-Yanadyl-Vanadat: Ba2(V 0)V 20 8 Crystal Structure Investigation of the Barium Vanadyl-Vanadate: Ba2(V 0 )V 20 8  
 Abstract    Single crystals of Ba2(V 0)V 20 8 have been prepared by solid state reactions of Ba2V 20 7, V 9O 1 and V ^ 05 in sealed silica tubes. This compound crystallizes with monoclinic symmetry, space group C 1 -P 2 ,, a = 8.1174(9), b = 5.9699(9), c = 9.2903(9) A , ß = 113.94(1)°, Z = 2. V 5+ shows tetrahedral coordination. V 4+ inside ^ [V (3)0 4] chains is characterized by a square pyramidal coordination with a short apical V-O distance of 1.6 A typically for vanadyl groups. Ba2(V 0)V 20 8 represents a new structure type and is not isotypic to Sr2(V 0)V 20 8. 
  Reference    Z. Naturforsch. 51b, 489—4 (1996); eingegangen am 22. August 1995 
  Published    1996 
  Keywords    Barium, Vanadium, Oxide, Crystal Structure 
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 Identifier    ZNB-1996-51b-0489 
 Volume    51 
71Author    Rolf Minkwitz, RaimUnd Bröchler, Hans PreutRequires cookie*
 Title    Low-Temperature Crystal Structure of the Inclusion Compound {[N(CH3)4+C1]2] * CH 3CN * h 2o  
 Abstract    The crystal structure of {[N(CH3)4+C1]2}-CFI3C N H 20 is reported. Cry-stalls are orthorhombic, space group Pnma, with a = 1622.9(15), b = 671.3(6), c = 1511.2(11) pm, V = 1646(2) 106 pm3 and Z = 4. 
  Reference    Z. Naturforsch. 51b, 599—601 (1996); eingegangen am 3. August 1995 
  Published    1996 
  Keywords    Preparation, Crystal Structure, Inclusion Compound 
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 Identifier    ZNB-1996-51b-0599_n 
 Volume    51 
72Author    Na2z, New Sodium, ZincateD. Trinschek, M. JansenRequires cookie*
 Title    Na2Zn02, ein neues Natriumzinkat  
 Abstract    By reacting Na20 , which was produced in situ from NaN3 and NaN02, with reactive ZnO in the solid state, the synthesis of Na2Z n02 has been achieved. Na2Zn02 is metastable up to about 750°C. The novel sodium zincate crystallizes in the spaceogroup P2,/c (No. 14) with the lattice parameters a = 7.7352(2), b = 5.9782(2), c = 5.7248(2)Ä, ß = 94.934(3)°, Z = 4. According to a single crystal structure determination it is an representative of the anti type of the Ln2S20 (Ln = Er, Tm, Yb, Dy) structure. 
  Reference    Z. Naturforsch. 51b, 711—714 (1996); eingegangen am 10. August 1995 
  Published    1996 
  Keywords    Sodium Zincates, Crystal Structure, Metastability 
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 Identifier    ZNB-1996-51b-0711 
 Volume    51 
73Author    Z. NaturforschRequires cookie*
 Title    A -P r 2S3, D -H o2S3 und E -Y b 2S3: Synthese und Einkristallstrukturuntersuchungen  
 Abstract    The oxidation of reduced chlorides (MC12) or chloride-hydrides (MC1HV) of the lanthani­ des with sulfur (700-850 °C, 7 d, sealed tantalum capsules or evacuated silica vessels) usually results in the formation of the sesquisulfides M2S3 as the main products. In the presence of appropriate fluxes (e.g., alkali halides), the products often are obtained as single crystals, and the flux decides which modification is favoured. Ternary halides of the trivalent lanthanides with the corresponding alkali metal can mostly be found as the second components. Crystal growth and structural investigations of thus produced single crystals of Pr2S3 (from PrClH() 67 + S + NaCl, 5:5:1, A type: orthorhombic, Pnma (No. 62), Z = 4, a = 748.22(5), b = 405.51(3), c = 1560.74(9) pm, R = 0.024, Rw = 0.020), Ho^S, (from U -H o^S , + KI, 1:1, D type: mono­ clinic, P 2xim (No. 12), Z = 6, a = 1746.15(9), b = 400.23(3), c = 1012.43(6) pm, ß = 98.529(4)°, R = 0.041, Rw = 0.035), and YbiS3 (from T-Yb^S^ + KI, 1:1, E type: trigonal, R 3c (No. 167), Z = 6, a = 674.97(2), c = 1820.11(9) pm'. R = 0.019, Rw = 0.018) are reported here. In accordance with the lanthanide contraction, the trivalent cations (M3+) exhibit sulfur coordination numbers of 7 and 8 in A -P r 2S3, 6 and 7 in D -H o 2S3, and 6 in E -Y b 2S3 (corundum-type structure). 
  Reference    Z. Naturforsch. 51b, 733—738 (1996); eingegangen am 4. Oktober 1994 
  Published    1996 
  Keywords    Lanthanides, Sesquisulfides, Synthesis, Crystal Structure 
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 TEI-XML for    default:Reihe_B/51/ZNB-1996-51b-0733.pdf 
 Identifier    ZNB-1996-51b-0733 
 Volume    51 
74Author    H. V., A. Fischerb, P. G. JonesbRequires cookie*
 Title    Eine unerwartete Synthese des Triphenyphosphazenium-chlorids, [(C6H5)3PNH2]+CI_ und eine Neubestimmung seiner Kristallstruktur  
 Abstract    Triphenylphosphazenium chloride has been prepared by the reaction of triphenylphos-phine with trimethylsilylazide in impure, wet dichloromethane. Yields are improved as stoi­ chiometric quantities of w ater are added. Colourless crystals are obtained by recrystallization from the same solvent. The crystals are triclinic, space group P I, Z=2, a = 894,6(3), b -979,8(3), c = 1142,9(4) pm, a = 107,27(3), ß = 93,70(3), y = 92,97(3)°. In the solid state the compound exists as [(C6H 5)3PNH2]+ cations, and Cl-anions. Dimeric units are formed by H-bonding. The crystal structure contains one molecule CH 2C12 per one molecule (C6H 5)3PNH2C1. The cation has a slightly irregular tetrahedral geometry around the P-atom with a relatively short P-N bond. 
  Reference    Z. Naturforsch. 51b, 865—868 (1996); eingegangen am 21. O ktober 1995 
  Published    1996 
  Keywords    Triphenylphosphazenium Chloride, Synthesis, Crystal Structure 
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 Identifier    ZNB-1996-51b-0865 
 Volume    51 
75Author    N. Stock, W. SchnickRequires cookie*
 Title    Synthese, Kristallstruktur und Eigenschaften von l,l>3 ?3 ?3 -Pentaam*n° -l  
 Abstract    oxo-lA 5 ,3A 5 -diphosphaz-2-en, (NH2)2 (0)P-N=P(NH2)3 Synthesis, Crystal Structure, and Properties of 1,1,3,3,3-Pentaam ino-l-oxo-l A 5 , 3 A 5 -diphosphaz-2-ene, (NH2)2(0)P-N =P(N H i)3 Coarse crystalline (NH2)2(0)P-N=P(NH2)3 is obtained from a NH;* saturated CH2C12 suspen­ sion of (NH2)2(0)P-N=P(NH2)3 NH4C1 at room temperature. (NH2)2(0)P-N=P(NH2)3 NH4C1 is synthesized" by slow addition of C12(0)P-N=PC13 to a solution of NH3 in CH2C12 at -78 °C. Excess NH4C1 is removed by treatment with HNEt2 followed by extraction with CH2C12. The crystal structure of (NH2)2(0)P-N=P(NH2)3 has been determined by single crystal X-ray methods (P2(/c; a = 1462.8(3), b = 944.8(2), c = 1026.9(2) pm, /3 = 110.69(3)°; Z = 8). In the unit cell there are two crystallographically unique molecules. They form a three dimensional network by intermolecular hydrogen bonding interactions (N-H- • N > 313 pm. N-H • 0 > 293 pm). The investigation of the thermal properties shows decomposition with evolution of NH3 above 80 °C. 
  Reference    Z. Naturforsch. 51b, 1079—1083 (1996); eingegangen am 7. Dezember 1995 
  Published    1996 
  Keywords    Aminophosphazene, Synthesis, Crystal Structure Precursor 
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 Identifier    ZNB-1996-51b-1079 
 Volume    51 
76Author    Wolfgang Czado, Ulrich MüllerRequires cookie*
 Title    (PPh4)4Sb8Br28 Tetraphenylphosphonium Ikosioctabromooctaantimonate(III), (PPh4)4Sb8Br28  
 Abstract    The title compound was obtained by the reaction of PPh4Br, Sb2Se3, and bromine in dichloro-methane. Its crystal structure was determined by X-ray diffraction. Crystal data: a = 1249.1(2), b = 1307.8(2), c = 2152.3(4) pm, a = 102.93(2), ß = 100.83(2), 7 = 100.42(2)°, Z = 2, triclinic, space group P I . (PPh4)4Sb8Br28 is isotypic with (PPh4)4Sb8I28. The Sb8Br284~ ion can be taken as the association product of eight SbBr3 molecules with four B r-ions. Each Sb atom has a distorted octahedral coordination with three shorter (252 to 274 pm) and three longer (300 to 353 pm) Sb-Br bonds. The octahedra share common edges in two parallel rows of four octahedra each. The arrangement of the 28 bromine atoms corresponds to a section of a closest packing of spheres. Tetraphenylphosphonium-ikosioctabromooctaantimonat(III), 
  Reference    Z. Naturforsch. 51b, 1245—1247 (1996); eingegangen am 22. März 1996 
  Published    1996 
  Keywords    Ocataikosabromooctaantimonate, Synthesis, Crystal Structure 
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 Identifier    ZNB-1996-51b-1245 
 Volume    51 
77Author    Joachim Pickardt, B. Ritta KühnRequires cookie*
 Title    Metallkomplexe mit Guanidinderivaten als Liganden  
 Abstract    Kristallstrukturen von [Zn(cnge)2(SCN)2] 2H20 und Zn(eoge)Br2 (enge = Cyanoguanidin; eoge = 1-Ethoxyiminomethylguanidin) M etal C om plexes with G uanidine D erivatives as Ligands: Crystal Structures o f [Zn(cnge)2(SC N)2]-2H20 und Z n(eoge)B r2 (cnge = C yanoguanidine; eoge = 1-Ethoxyim inom ethylguanidine) Crystals of |Zn(cnge)2(SCN)2]-2H20 (1) were obtained by evaporation of an aqueous solution 
  Reference    Z. Naturforsch. 51b, 1469—1472 (1996); eingegangen am 3. April 1996 
  Published    1996 
  Keywords    Cyanoguanidine, Zinc Complexes, Crystal Structures 
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 Identifier    ZNB-1996-51b-1469 
 Volume    51 
78Author    StefanH. Orstm, AnnW. Olfgang SchnickRequires cookie*
 Title    Synthese  
 Abstract    , K rista llstru k tu r und Eigenschaften von 1 ,1 , 1 > 3 * 3 , 3 -H e x a a m i n o -lA 5,3A5-diphosphazenium ehlorid[(N H 2)3PNP(NH2)3]Cl Synthesis, C rystal Structure, and Properties of 1,1,1,3,3,3-Hexaam ino-1 A5,3A5-diphosphazenium Chloride [(N H 2)3PN P(N H 2)3]C1 [(NH2)3PNP(NH2)3 ]C1 has been prepared by a three step synthesis. The last step is the ammo-nolysis of [C13PNPC13]C1. Single crystals of 1,1,1,3,3,3-hexaamino-1 A \ 3As-diphosphazenium chloride were obtained from an acetonitrile solution in a temperature gradient between 60 °C and room temperature. Between room temperature and -1 0 0 °C [(NH2)3PNP(NH2)3]C1 is sub­ ject to a phase transition. Therefore, the crystal structure was determined by single crystal X-ray methods at room temperature (P i, a = 584.7(1) pm, b = 732.1(1) pm, c = 1092.0(2) pm. q = 71.05(3)°, ß = 76.36(3)°, 7 = 89.83(3)°, Z = 2, R = 4.75 %, wR = 2.47 %). The cation [(NH2)3PNP(NH2)3]+ is built up by two corner sharing PN4 tetrahedra. Remarkably short P-N bonding distances have been observed and both PN4 tetrahedra exhibit a significant distortion resulting in two large and four small N-P-N bond angles. 
  Reference    Z. Naturforsch. 51b, 1732—1738 (1996); eingegangen am 26. Juni 1996 
  Published    1996 
  Keywords    Aminophosphazenes, Synthesis, Crystal Structure 
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 Identifier    ZNB-1996-51b-1732 
 Volume    51 
79Author    G. Rebe, Frank Weller, Kurt Dehnicke, ProfRequires cookie*
 Title    Jutta  
 Abstract    N-Iodo-triphenylphosphaneimine, Ph3PNI, has been prepared by thermolysis of the donor acceptor complex [Me3SiNPPh3-ICl] in boiling acetonitrile in the presence of potassium fluo­ ride. Both compounds have been characterized by IR spectroscopy and by crystal structure determinations. [Me3SiNPPh3 ICl]: Space group P I, Z = 2, a = 888.3(1), b = 1070.7(1), c = 1310.2(1) pm, a = 9 5 .15(1)°, ß = 108.67(1)°, 7 = 97.78(1)° at 20°C. The complex has a molecular structure in which the N atom of the phosphaneimine is connected with the iodine atom of the IC1 molecule in a linear arrangement N-I-Cl with bond lengths N-I = 232.7 pm, I-Cl = 255.37 pm. Ph3PNI: Space group P2,/n, Z = 4, a = 952.8(1), b = 1800.8(2), c = 1003.6(1) pm, ß = 110.25(1)° at -50°C. The compound forms monomeric molecules with bond lengths PN = 159.1 pm, I-N = 205.6 pm and an INP bond angle of 113.3°. N-Iod-triphenylphosphanimin. Synthese und Kristallstrukturen von [Me3SiNPPh3 ICl] und Ph3PNI 
  Reference    Z. Naturforsch. 51b, 1739—1743 (1996); eingegangen am 12. April 1996 
  Published    1996 
  Keywords    Phosphaneimine Complexes, Synthesis, Crystal Structure 
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 Identifier    ZNB-1996-51b-1739 
 Volume    51 
80Author    Christian Meyer3, Dietrich Mootza, Birgit Bäckb, Rolf MinkwitzbRequires cookie*
 Title    Bis(trifluormethyl)disulfan und -trisulfan: Molekülgeometrie im festen Zustand [1] Bis(trifluoromethyl)disulfane and Trisulfane: Molecular Geometry in the Solid State [1]  
 Abstract    The solid-state structures of the low-melting compounds bis(trifluoromethyl)disulfane (CF3SSCF3, triclinic, space group P I, Z = 2) and bis(trifluoromethyl)trisulfane (CF3SSSCF3, monoclinic, space group C2/c, Z = 4) have been determined on single crystals with M oK a radiation at -160°C. The trisulfane has trans conformation. The geometry of both molecules agrees well with results of electron diffraction on the gaseous state. A comparison is made also with the crystal structures of the related molecules CF3TeTeCF3 and CF3OOOCF3. 
  Reference    (Z. Naturforsch. 52b, 69—71 [1997]; eingegangen am 15. Juli 1996) 
  Published    1997 
  Keywords    Conformation, Crystal Structure, Sulfane 
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 TEI-XML for    default:Reihe_B/52/ZNB-1997-52b-0069.pdf 
 Identifier    ZNB-1997-52b-0069 
 Volume    52 
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