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'Crystal Structure' in keywords Facet   section ZfN Section B:Volume 043  [X]
Facet   Publication Year 1988  [X]
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1988[X]
41Author    Yuzo Nishida, Naoko Oshino, Tadashi TokiiRequires cookie*
 Title    Crystal Structure and Magnetic Property of the Binuclear Manganese(III) Complex with /u-Acetate and Di-ji-Alkoxo Bridges  
 Abstract    Binuclear manganese(III) complex, [Mn : L(u-OCH 3)0<-CH 3 COO)(OHCH : ,)]ClO 4 was pre-pared and characterized in terms of crystal structure determination, magnetic measurement, and ESR spectroscopy, where H 3 L represents the Schiff base derived from salicylaldehvde and 1,5-diamino-3-pentanol. 
  Reference    Z. Naturforsch. 43b, 472—474 (1988); received November 9/December 17 1987 
  Published    1988 
  Keywords    Binuclear Manganese(III) Complex, Crystal Structure, ESR Spectra, Magnetic Property 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-0472.pdf 
 Identifier    ZNB-1988-43b-0472 
 Volume    43 
42Author    Manfredo Hörner, Wolfgang Hiller, Joachim Strähle, GeorgeM. SheldrickRequires cookie*
 Title    Synthese, Eigenschaften und Kristallstruktur von (NH 4 )NbOBr 4 Synthesis, Properties and Crystal Structure of (NH 4 )NbOBr 4  
 Abstract    (NH 4)NbOBr 4 is obtained as air sensitive, light red crystals from NH 4 Br and NbBr 5 in a sealed glass ampoule at 420 °C, whereby the oxygen presumably originates from the glass surface. The compound crystallizes in the monoclinic space group C2/m with a — 1269.9(1), b = 1384.7(2). c = 773.0(2) pm, ß = 114.44(2)° and Z = 6. The structure is built up by NH 4 + cations and polymeric NbOBr 4 anions. Symmetrical linear oxo bridges with Nb-O = 199 pm connect square planar NbBr 4 units to form endless chains arranged in planes parallel (010). Neighbouring NbBr 4 units are in eclipsed as well as staggered orientations. The NH 4 + cations are located between the planes of parallel NbOBr 4 " chains. The vibrational frequencies of the IR and Raman spectrum are assigned. 
  Reference    Z. Naturforsch. 43b, 981—984 (1988); eingegangen am 25. März 1988 
  Published    1988 
  Keywords    Ammonium Tetrabromooxoniobate(V), Synthesis, Crystal Structure, Raman Spectra, IR Spectra 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-0981.pdf 
 Identifier    ZNB-1988-43b-0981 
 Volume    43 
43Author    Jörg Adel, Frank Weller, Kurt DehnickeRequires cookie*
 Title    Synthese und Kristallstrukturen der spirocyclischen Polyselenido-Komplexe [Na-15-Krone-5] 2 [M(Se 4 ) 2 ] mit M = Zink, Cadmium und Quecksilber Sythesis and Crystal Structures of the Spirocyclic Polyselenido Complexes [Na-15-Crown-5] 2 [M(Se 4 ) 2 ] with M = Zink, Cadmium, and Mercury  
 Abstract    The title compounds have been prepared by reactions of the metal acetates of zink, cadmium, and mercury with ethanolic solutions of sodium polyselenides in the presence of 15-crown-5. They form dark red crystals, which were characterized by their IR specta as well as by X-ray crystal structure determinations. All complexes [Na-15-crown-5] 2 [M(Se 4) 2 ] with M = Zn (1), Cd (2), Hg (3) crystallize isotypically in the space group C2/c with 4 formula units per unit cell. In the anions [M(Se 4) 2 ] 2 ^ the metal atoms are coordinated tetrahedrally by four selenium atoms of two Se 4 2 ~ units, thus forming a spiro-bicyclus. The complex cations [Na-15-crown-5] + have a Na---Se contact of approximately 299 pm with two selenium atoms of a MSe 4 group, allowing formulation of triple ion species. 
  Reference    Z. Naturforsch. 43b, 1094—1100 (1988); eingegangen am 4. Mai 1988 
  Published    1988 
  Keywords    Polyselenide Complexes of Zink, Cadmium, Mercury, Syntheses, Crystal Structure 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-1094.pdf 
 Identifier    ZNB-1988-43b-1094 
 Volume    43 
44Author    Ekkehard Fluck, Peter Kuhm, Heinz RiffelRequires cookie*
 Title    [l,4,2]Diazaphospholidine [l,4,2]Diazaphospholidines  
 Abstract    Bis(diethylamino)phosphanylacetylen reacts with N.N'-dimethyl thiourea to give 2-diethyl-amino-l,4-dimethyl-3-methylene-[l,4,2]diazaphospholidine-5-thion (2) besides the [1.3.4]thi-azaphospholidine (1). The latter compound is converted into 2 by heating. Reaction of 2 with various reagents yields other members of the title compound class. All new compounds are characterized by some reactions and their NMR and IR spectra. In addition, the results of an X-ray structure analysis of 2-diethylamino-l ,4-dimethyl-3-methylene-2-thioxo-[l ,4.2]diazaphos-pholidine-5-thion (5) are reported. 
  Reference    Z. Naturforsch. 43b, 1481—1489 (1988); eingegangen am 17. Mai 1988 
  Published    1988 
  Keywords    [l, 4, 2]Diazaphospholidines, NMR Spectra, Crystal Structure 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-1481.pdf 
 Identifier    ZNB-1988-43b-1481 
 Volume    43 
45Author    Jörn Müller, Matthias Tschampel, Carl KrügerRequires cookie*
 Title    Rhodium-zentrierte Bildung eines Cyclobutenyl-Liganden und Umlagerung in einen Cyclopentadienyl-Komplex Rhodium-centered Formation of a Cyclobutenyl Ligand and Rearrangement to a Cyclopentadienyl Complex  
 Abstract    Cyclization of two diphenylacetylene molecules occurs if [(cod)RhCl] 2 (cod = 1.5-cyclooc-tadiene) is treated with methyllithium in the presence of tolane. The isolated (cod)Rh complex 2 contains an e*o-methyl-tetraphenylcyclobutenyl ligand and was characterized by X-ray diffraction analysis. Thermolysis of 2 in acetonitrile causes ring expansion of the methylcyclobutenyl unit with formation of the tretraphenylcyclopentadienyl complex 3 together with 3-methyl-tet-raphenylcyclobutene. Mechanistic aspects are discussed as well as spectroscopic data of the new compounds. 
  Reference    Z. Naturforsch. 43b, 1519—1523 (1988); eingegangen am 13. Juni 1988 
  Published    1988 
  Keywords    Methyltetraphenylcyclobutenyl Rhodium Complexes, Tetraphenylcyclopentadienyl Rhodium Complexes, NMR Spectra, Crystal Structure 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-1519.pdf 
 Identifier    ZNB-1988-43b-1519 
 Volume    43 
46Author    Wolfgang Hönle, Juliane Wolf, Hans Georg, SchneringRequires cookie*
 Title    Substituierte Heptaarsane(3)  
 Abstract    As 7 (Mme 3)3 (M = Si, Ge, Sn) mit Nortricyclenstruktur Substituted Heptaarsanes(3) As 7 (Mme 3) 3 (M = Si, Ge, Sn) with Nortricyelene Structure The heptaarsanes(3) As 7 (Mme 3) 3 (M = Si, Ge, Sn) with nortricyclene structure have been synthesized by heterogeneous and homogeneous reactions from K 3 As 7 and Rb 3 As 7 , respectively, with Mme 3 Cl. The crystal structures have been determined. The compounds are isotypic and crystallize in unit cells of R3 symmetry, containing pairs of enantiomers. The bond lengths d(As—As) in the nortricyclene skeleton are nearly uneffected by the substituents and show the sequence typical for covalent nortricyclenes: d(basal) = 244.3 pm > d(basal-equatorial) = 242.7 pm > d(equatorial-apical) = 240.7 pm (mean values). The spread-off of the Mme, sub-stituents decreases as going from P 7 to As 7 skeletons as well as with increasing size of M. 
  Reference    Z. Naturforsch. 43b, 219—223 (1988); eingegangen am 26. Oktober 1987 
  Published    1988 
  Keywords    Heptaarsa-nortricyclene, Crystal Structure, Silyl-, Germyl-and Stannyl-Substituted Heptaarsanes(3) 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-0219.pdf 
 Identifier    ZNB-1988-43b-0219 
 Volume    43 
47Author    Wolfgang Saak, Detlev Haase, Siegfried PohlRequires cookie*
 Title    Darstellung, Reaktionen und Kristallstrukturen von (Me 3 NCH 2 Ph) 2 Fe 2 I 6 und Fe 2 l4(SPPh 3 ) 2 * PhMe (Ph = C 6 H 5 , Me = CH 3 ) Preparation, Reactions, and Crystal Structure of (Me 3 NCH 2 Ph) 2 Fe 2 I 6 and Fe 2 I 4 (SPPh 3 ) 2 -PhMe (Ph = C 6 H 5 , Me = CH 3 )  
  Reference    Z. Naturforsch. 43b, 289—294 (1988); eingegangen am 23. September/6. November 1987 
  Published    1988 
  Keywords    Dinuclear Iron(II) Complexes, Iodoferrate, Phosphin Sulfide Complex of Iron(II), Synthesis, Crystal Structure 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-0289.pdf 
 Identifier    ZNB-1988-43b-0289 
 Volume    43 
48Author    Hans-U Hummel, Hermann MeskeRequires cookie*
 Title    Über Verbindungen subvalenter Hauptgruppenmetallkationen mit Dithiolaten, 1. Mitteilung. Das dimorphe Blei(II)-l,l-dicyanoethylen-2,2-dithiolat: Darstellung und Kristallstrukturen Compounds of Subvalent Main Group Metal Cations with Dithiolates, 1. Contribution. Dimorphie Lead(II) l,l-Dicyanoethylene-2,2-dithiolate: Preparation and Crystal Structures  
 Abstract    By reaction of Pb(CH,COO) 2 -3 H 2 0 with Na 2 S 2 C=C(CN) 2 -3 H 2 0 in water, a-PbS 2 C=C(CN) 2 is obtained. Hydrothermal conditions give small crystals of the a-and /3-phase. The crystal structures of the two phases have been determined. The a-phase is monoclinic with space group P2Jn and a = 11.879(5), b = 12.027(5), c = 4.655(1) Ä, ß = 96.94(3)°, Z = 4. The compound contains PbS 2 C 4 N 2 molecules with Pb—S = 2.66 and 2.90 Ä. Two molecules are connected to dimers with Pb-Pb = 4.44 Ä. The /3-phase also crystallizes monoclinically, space group C2/c, a = 9.613(1), b = 13.579(1), c -16.052(2) Ä, ß = 98.36°, and Z = 12. There are two independent lead positions, with the metals integrated in PbS 2 C = C(CN) 2 groups with a stereochemically active lone-pair, and dimers Pb 2 (S 2 C 4 N 2) 2 with Pb-Pb distance = 3.80 Ä. 
  Reference    Z. Naturforsch. 43b, 389—398 (1988); eingegangen am 21. Dezember 1987 
  Published    1988 
  Keywords    Lead(II) l, l-Dicyanoethylene-2, 2-dithiolate, a-and /3-Phase, Synthesis, Crystal Structure 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-0389.pdf 
 Identifier    ZNB-1988-43b-0389 
 Volume    43 
49Author    Edmund Hartmann, Joachim SträhleRequires cookie*
 Title    Synthese und Kristallstruktur von [l,3-Bis(4-ethoxyphenyl)triazenido]pyridino-silber(I), einem dimeren Komplex mit kurzem Silber-Silber-Kontakt Synthesis and Crystal Structure of [l,3-Bis(4-ethoxyphenyl)triazenido]pyridino Silver(I), a Dimeric Complex with a Short Silver-Silver Contact  
  Reference    Z. Naturforsch. 43b, 525—528 (1988); eingegangen am 22. Dezember 1987 
  Published    1988 
  Keywords    Bis[l, 3-Bis(4-ethoxyphenyl)triazenido-pyridino Silver(I)], Synthesis, Crystal Structure 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-0525.pdf 
 Identifier    ZNB-1988-43b-0525 
 Volume    43 
50Author    Karin Völp, Gerhard Baum, Werner Massa, Kurt DehnickeRequires cookie*
 Title    [Na-15-Krone-5][MoF 2 Cl2(N 3 S2)]; Synthese und Kristallstruktur [Na-15-Crown-5][MoF 2 Cl 2 (N 3 S 2 )]; Synthesis and Crystal Structure  
 Abstract    The cyclothiazeno complex [Na-15-crown-5][MoF 2 Cl 2 (N 3 S 2)] has been prepared by the reaction of sodium fluoride with [MOC1 3 (N 3 S 2)] 2 in acetonitrile solution in the presence of [15-crown-5], The compound was characterized by its IR spectrum as well as by an X-ray structure determina-tion (3560 observed independent reflexions, R = 0.039). Crystal data: monoclinic, P2,//?, Z = 4; a = 1044.8(2); b = 1513.7(2); c = 1363.8(3) pm; ß = 104.33(2)°. The structure consists of ion pairs, in which the sodium atom is seven-coordinated by the oxygen atoms of the crown ether molecule and by the two fluorine ligands of the [MOF 2 C1 2 (N 3 S 2)]~ unit. The molybdenum atom is a member of the planar MON 3 S 2 ring; the fluorine atoms are coordinated in trans position to the nitrogen atoms of the cyclothiazeno ring. 
  Reference    Z. Naturforsch. 43b, 1235—1239 (1988); eingegangen am 7. Juni 1988 
  Published    1988 
  Keywords    Fluoro-Chloro-Cyclothiazeno Complex of Molybdenum(VI), Synthesis, IR Spectra, Crystal Structure 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-1235.pdf 
 Identifier    ZNB-1988-43b-1235 
 Volume    43 
51Author    Evamarie Hey, Christina Ergezinger, Kurt DehnickeRequires cookie*
 Title    Die Reaktion von N  
 Abstract    ,N,N'-Tris(trimethylsilyI)benzamidin mit Kupfer(II)chlorid. Kristallstruktur von {C 6 H 5 -C(NSiMe 3) 2 CuCl [C 6 H 5 -C(NSiMe 3)(NHSiMe 3)]} The Reaction of N,N,N'-Tris(trimethylsilyl)benzamidine with Copper(II) Chloride. Crystal Structure of {C 6 H 5 —C(NSiMe 3)->CuCl • [C 6 H 5 -C(NSiMe 3)(NHSiMe 3)]} 
  Reference    Z. Naturforsch. 43b, 1679—1682 (1988); eingegangen am 27. Juni 1988 
  Published    1988 
  Keywords    N, N'-Bis(trimethylsilyl)benzamidinato-copper Chloride-N, N'-bis(trimethylsilyl)benzamidine Adduct, Synthesis, IR Spectrum, Crystal Structure 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-1679_n.pdf 
 Identifier    ZNB-1988-43b-1679_n 
 Volume    43 
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