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'Crystal Structure Dinuclear Ti S and Ti Se Complexes' in keywords Facet   section ZfN Section B  [X]
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1988 (1)
1Author    PaulG. Maué, Dieter FenskeRequires cookie*
 Title    Zur Reaktion von [Cp 2 TiCl 2 ] und [CpTiC! 3 ] mit E(SiMe 3 ) 2 (E = S, Se) Die Kristallstrukturen von [Cp 3 Ti 2 S 2 Cl], [Cp 4 Ti 2 S 2 Cl 2 ], [Cp 3 Ti 2 Se 2 CI] und [Cp4Ti 4 Se 7 0] Reaction of [Cp 2 TiCl 2 ] and [CpTiCl 3 ] with E(SiMe 3 ) 2 (E = S. Se) The Crystal Structures of [Cp 3 Ti 2 S 2 Cl], [Cp 3 Ti 2 S 2 Cl 2 ], [Cp 3 Ti 2 Se 2 Cl] and [Cp 4 Ti 4 Se 7 0]  
 Abstract    The reaction of [Cp 2 TiCl 2 ] with E(SiMe 3) 2 leads to dinuclear Ti complexes. In [Cp 3 Ti 2 S 2 Cl] (1) and [Cp 3 Ti 2 Se 2 Cl] (3) two // 2 -S(Se) ligands bridge the Cp 2 Ti and CpTiCl units, respectively in contrast to these, [Cp 4 Ti 2 S 2 Cl 2 ] (2) contains a // 2 V-S 2 bridge connecting two Cp : TiCl fragments. A similar reaction of [CpTiCl 3 ] with Se(SiMe 3) 2 leads to the tetranuclear cluster [Cp 4 Ti 4 Se 7 0] (4). 4 consists of a Ti 4 -tetrahedron which encloses an oxygen atom. 
  Reference    Z. Naturforsch. 43b, 1213—1218 (1988); eingegangen am 11. Mai 1988 
  Published    1988 
  Keywords    X-Ray, Crystal Structure Dinuclear Ti-S and Ti-Se Complexes, Tetranuclear Ti Cluster 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-1213.pdf 
 Identifier    ZNB-1988-43b-1213 
 Volume    43