| | 1 | Author
| RolfW. Saalfrank3, Roland Harbig3, Oliver Struck, Frank Hampel3, Eva Maria Petersc, Karl Petersc, HansG. Eorg, Von Schneringc | Requires cookie* | | | Title
| Eindimensionale Kupfer(II)-Koordinationspolymere: Kristall-Engineering durch variable Verknüpfungsmuster [1] One Dimensional Copper(II) Coordination Polymers: Crystal Engineering through Variable Types of Linkage [1]  | | | | Abstract
| of a methanolic copper(II) acetate solution with tetrazolyl enol derivatives 2a or 2b leads to the formation of the corresponding lD-coordination polymer ^[CuL2] 3a and pseudo lD-coordination polymer [CuL2]2 3b, respectively. On the contrary, reaction of 2c with methanolic copper(II) acetate solution yields OH-bridged lD-coordination polymer ^[CuL2(MeOH)2l 3c. Single-crystal X-ray diffraction of the supramolecular species 3 established unequivocally the structures of the stairlike coordination compounds. Reaction of a methanolic copper(II) acetate solution with amidotetrazole derivative 6 leads to the formation of the lD-coordination polymer ^,[CuL2] 7. The structure of 7 has been established by X-ray structure analysis. | | | |
Reference
| (Z. Naturforsch. 52b, 125—134 [1997]; eingegangen am 6. August 1996) | | | |
Published
| 1997 | | | |
Keywords
| Tetrazolyl Enols, Coordination Polymers ID, Copper Complexes, Self-Assembly, Crystal Engineering Reaction | | | |
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