| 1 | Author | A. E. Lavat, S. B. Etcheverry, E. J. Baran | Requires cookie* |
| Title | Kristallographisches und spektroskopisches Verhalten einiger gemischter Phosphat/Vanadat-Fluoroapatite Crystallographic and Spectroscopic Behaviour of Some Mixed Phosphate/Vanadate Fluoroapatites  | ||
| Abstract | Crystallographic data for m ixed phosphate/vanadate fluoroapatites o f the type M 1o(P0 4)6_J(V 0 4)AF2 (with M = Ca, Sr, Ba and x = 1—3) have been obtained from X-ray powder data. The only structural effect observed is a continuous increase of unit cell dim ensions with increased vanadate incorporation. The IR and Raman spectra show that the V 0 43 incorporation has a negligible effect on the strength of the P —O bonds, although a small bond weakening for both tetrahedral oxoanions is observed as the unit cell volum e increases. The results are com par able to those reported earlier for similar mixed hydroxyapatites and suggest that the fluoroapatite lattice can be considered as a good "m odel" for the vertebrate hard tissues. | ||
| Reference | Z. Naturforsch. 41b, 987 (1986); eingegangen am 15. April 1986 | ||
| Published | 1986 | ||
| Keywords | Mixed A patites, Crystal Data, IR Spectra, Raman Spectra | ||
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