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'Crown Ether' in keywords Facet   section ZfN Section B:Volume 038  [X]
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1983 (1)
1Author    FranzL. Dickert, Walter GumbrechtRequires cookie*
 Title    Komplexbildung und Ligandenfluktuation im System Co (II) / [18] Krone-6 Complex Formation and Ligand Fluctuation in the System Co(II)/[18]crown-6  
 Abstract    The ligand properties of [18]crown-6 towards Co(II) ions were studied by iH and 13 C NMR spectroscopy in nitromethane and nitromethane/methanol. The complexes [Co([18]crown-6)] ++ and mer-[Co([18]crown-6)(CH30H)3] ++ which were detected in solu-tion show ligand fluctuations on the NMR time scale. For the mixed complex a crown ether rotation occurs. Additionally, a synchronous process between the movement of the macrocyclic ligand and the dissociation reaction of methanol from the metal ion is observed. 
  Reference    Z. Naturforsch. 38b, 934—937 (1983); eingegangen am 28. März/27. April 1983 
  Published    1983 
  Keywords    Crown Ether, Complex Formation, Ligand Fluctuation, NMR Spectroscopy 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-0934.pdf 
 Identifier    ZNB-1983-38b-0934 
 Volume    38