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'Cross relaxation' in keywords Facet   Publication Year 2000  [X]
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2000[X]
1Author    David StephensonRequires cookie*
 Title    Two-dimensional Two Contact Double Resonance Spectroscopy  
 Abstract    A two-dimensional spectroscopic technique is presented. Application of the technique to de-termine all the relaxation rates for a multi-level quadrupole system is discussed along with ex-perimental requirements. Theoretical and experimental data are analyzed for the 14 N, three level, spin 1 system. The analysis shows that all three relaxation rates can be obtained from a single two-dimensional spectrum, and that only 3 peaks in the 3 x 3 two-dimensional intensity matrix are needed to completely specify the problem. The 4-level spin 3/2 system is also examined. In theory, all six relaxation rates can be independently evaluated (for a suitable system) without necessitating measurement at the low frequency Zeeman separated levels. 
  Reference    Z. Naturforsch. 55a, 79—82 (2000); received September 11 1999 
  Published    2000 
  Keywords    NQR, 14 N, Relaxation, Two-dimensional, Cross-relaxation 
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 TEI-XML for    default:Reihe_A/55/ZNA-2000-55a-0079.pdf 
 Identifier    ZNA-2000-55a-0079 
 Volume    55 
2Author    Hiroyuki IshidaRequires cookie*
 Title    H NMR Study of Ionic Motions in High Temperature Solid Phases of (CH 3 NH 3 ) 2 ZnCl 4  
 Abstract    The reorientation of the tetrahedral complex anion ZnCl 4 2-and the self-diffusion of the cation in (CH 3 NH3) 2 ZnCl4 were studied by 'H NMR spin-lattice relaxation time ('H T X) experiments. In the second highest-temperature phase, the temperature dependence of *H T X observed at 8.5 MHz could be explained by a magnetic dipolar-electric quadrupolar cross relaxation between 'H and chlorine nuclei, and the activation energy of the anion motion was determined to be 105 kJ mol -1 . In the highest-temperature phase, the activation energy of the self-diffusion of the cation was determined to be 58 kJ mol -1 from the temperature and frequency dependence of 'H T X . 
  Reference    Z. Naturforsch. 55a, 412—114 (2000); received January 8 2000 
  Published    2000 
  Keywords    Nuclear Magnetic Resonance, Molecular Motion, Cross Relaxation, (C^N^^ZnCfj 
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 TEI-XML for    default:Reihe_A/55/ZNA-2000-55a-0412.pdf 
 Identifier    ZNA-2000-55a-0412 
 Volume    55