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'Copper I Complexes' in keywords Facet   Publication Year 1982  [X]
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1Author    Ulf Thewalt, Bernhard MüllerRequires cookie*
 Title    S4X4 and its Derivatives: Preparation. Structure and Thermolysis of CuBr * S4X4  
 Abstract    The crystalline black polymeric Cui complex CuBr • S4N4 can be prepared in high yield from Cu(NÜ3)2 • 3 HoO, NH4Br and S4N4 in methanol. An X-ray structure analysis shows that it is isostructural with CuCl • S4N4. The crystals contain [CuBr]^ chains and the Cu atoms of adjacent chains are bridged by S4N4 groups. The Cu atoms have an almost tetrahedral coordination. Tho l,3-N,N'-bonded S4N4 group has the same conformation and, within narrow limits, the same dimensions as free S4N4. Thermolysis of CuBr • S4N4 at 180 C C yields among other products CuBr, S4N4, and S2N2. 
  Reference    Z. Naturforsch. 37b, 828—831 (1982); eingegangen am 17. Februar 1982 
  Published    1982 
  Keywords    Copper(I) Complex, Tetrasulfurtetranitrid Adduct, Disulfurdinitrid, Molecular Structure, Inorganic Polymer 
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 TEI-XML for    default:Reihe_B/37/ZNB-1982-37b-0828.pdf 
 Identifier    ZNB-1982-37b-0828 
 Volume    37