| | 1 | Author
| Ulf Thewalt, Bernhard Müller | Requires cookie* | | | Title
| S4X4 and its Derivatives: Preparation. Structure and Thermolysis of CuBr * S4X4  | | | | Abstract
| The crystalline black polymeric Cui complex CuBr • S4N4 can be prepared in high yield from Cu(NÜ3)2 • 3 HoO, NH4Br and S4N4 in methanol. An X-ray structure analysis shows that it is isostructural with CuCl • S4N4. The crystals contain [CuBr]^ chains and the Cu atoms of adjacent chains are bridged by S4N4 groups. The Cu atoms have an almost tetrahedral coordination. Tho l,3-N,N'-bonded S4N4 group has the same conformation and, within narrow limits, the same dimensions as free S4N4. Thermolysis of CuBr • S4N4 at 180 C C yields among other products CuBr, S4N4, and S2N2. | | | |
Reference
| Z. Naturforsch. 37b, 828—831 (1982); eingegangen am 17. Februar 1982 | | | |
Published
| 1982 | | | |
Keywords
| Copper(I) Complex, Tetrasulfurtetranitrid Adduct, Disulfurdinitrid, Molecular Structure, Inorganic Polymer | | | |
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| ZNB-1982-37b-0828 | | | | Volume
| 37 | |
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