| | 1 | Author
| Susanne Maier, Wolfgang Hiller, Joachim Strähle, Christina Ergezinger, Kurt Dehnicke | Requires cookie* | | | Title
|  | | | | Abstract
| The copper(I)amidinato complex Cu 2 [Ph-C(NSiMe 3) 2 ] ; has been prepared by the reaction of CuCl with N.N,N'-tris(trimethylsilyl)benzamidine in boiling acetonitrile. forming white crystals. The compound was characterized by its IR spectrum as well as by an X-ray structure determina-tion. Crystal data: space group PI, Z = 2 (2851 observed independent reflexions, R = 0.047). Lattice dimensions at 20 °C: a = 1135.0(3); b = 1219.6(4); c = 1372.4(4) pm; a = 106.74(3)°; ß = 107.92(4)°; y = 91.40(4)°. The compound forms dimeric molecules with a short Cu--Cu contact of 242 pm and two chelating amidinato ligands with Cu-N bond lengths of (averaged) 189.0 pm and bond angles N —C—N of 124.1°. | | | |
Reference
| Z. Naturforsch. 43b, 1628—1632 (1988); eingegangen am 11. August/30. September 1988 | | | |
Published
| 1988 | | | |
Keywords
| Synthesis, X-Ray, Copper(I) Amidinato Complex | | | |
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| default:Reihe_B/43/ZNB-1988-43b-1628.pdf | | | | Identifier
| ZNB-1988-43b-1628 | | | | Volume
| 43 | |
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