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'Copper I Amidinato Complex' in keywords
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1988 (1)
1Author    Susanne Maier, Wolfgang Hiller, Joachim Strähle, Christina Ergezinger, Kurt DehnickeRequires cookie*
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 Abstract    The copper(I)amidinato complex Cu 2 [Ph-C(NSiMe 3) 2 ] ; has been prepared by the reaction of CuCl with N.N,N'-tris(trimethylsilyl)benzamidine in boiling acetonitrile. forming white crystals. The compound was characterized by its IR spectrum as well as by an X-ray structure determina-tion. Crystal data: space group PI, Z = 2 (2851 observed independent reflexions, R = 0.047). Lattice dimensions at 20 °C: a = 1135.0(3); b = 1219.6(4); c = 1372.4(4) pm; a = 106.74(3)°; ß = 107.92(4)°; y = 91.40(4)°. The compound forms dimeric molecules with a short Cu--Cu contact of 242 pm and two chelating amidinato ligands with Cu-N bond lengths of (averaged) 189.0 pm and bond angles N —C—N of 124.1°. 
  Reference    Z. Naturforsch. 43b, 1628—1632 (1988); eingegangen am 11. August/30. September 1988 
  Published    1988 
  Keywords    Synthesis, X-Ray, Copper(I) Amidinato Complex 
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 TEI-XML for    default:Reihe_B/43/ZNB-1988-43b-1628.pdf 
 Identifier    ZNB-1988-43b-1628 
 Volume    43