| | 1 | Author
| LiAnsgar Bach, Michael Hoyer, Hans Hartl | Requires cookie* | | | Title
| Darstellung und Kristallstruktur der oligomeren Iodo-d10-metallate(II) [M(I)(CH3CN)4]4[Cd6I16] * 1,5 CH3CN mit M(I) = Cu, Li Synthesis and Crystal Structure of the Oligomeric Iodo-d10-Metalates(II) [M(I)(CH3CN)4]4[Cd6I16] * 1.5 CH3CN with M(I) = Cu  | | | | Abstract
| The reaction of Cul or Lil with Cdl2 in the polar solvent acetonitrile results in the formation of the iodocadmates [Cu(CH3CN)4]4[Cd6I16] • 1.5CH3CN (1) and [Li(CH3CN)4]4[Cd6I 16] • 1.5CH3CN (2) with the oligomeric anion [Cd6I16]4~. This new type of halometallate anion, which is found in both isotypic structures, is built up by six alternating corner and edge sharing Cdl4 tetrahedra. 1: Space group PI (No 2), a = 838.5(4), b = 1465.9(9), c = 1929.8(6) pm, q = 93.01(3), ß = 99.13(3), 7 = 105.11(3)°; 1: Space group P i (No 2), a = 841.7(8), b = 1470(9), c = 1945.5(9) pm, a = 93.27(5), ß = 99.13(5), 7 = 104.83(5)°. | | | |
Reference
| Z. Naturforsch. 52b, 1497—1500 (1997); eingegangen am 15. September 1997 | | | |
Published
| 1997 | | | |
Keywords
| Iodocadmates, Lithium Iodocadmate, Copper Iodocadmate, Crystal Structure | | | |
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| default:Reihe_B/52/ZNB-1997-52b-1497.pdf | | | | Identifier
| ZNB-1997-52b-1497 | | | | Volume
| 52 | |
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