| | 1 | Author
| RolfW. Saalfrank3, Oliver Struck3, Karl Petersb, HansG. Eorg, Von Schneringb | Requires cookie* | | | Title
| Synthese und Struktur diastereomerer, zweikerniger Kupferkomplexe [1] Synthesis and Structure of Diastereomerie Dinuelear C opper Complexes [1]  | | | | Abstract
| Depolym erisation of a copper(II)/pyrrolidine-based 2D -polym er 2 by 4.4'-bipyridyl [molar ratio: 2 (C u L 2) : l (Bipy)] and recrystallisation o f the reaction product leads to two visually distinguishable crystal charges, composed of dark green octahedra m eso-4 and light green rod-shaped crystals racem-5. Separation of the conglom erate of the morphologically different crystals is accomplished by pick out. The structure of the dinuelear complex racem-5 has been established unambigously by X-ray structure analysis. EPR and susceptibility measure ments of mixtures of complex meso-4 and racem-S indicate that there is no interaction be tween the two copper(II) centres. | | | |
Reference
| Z. Naturforsch. 49b, 1410—1414 (1994); eingegangen am 17. März 1994 | | | |
Published
| 1994 | | | |
Keywords
| Coordination Polymers, Depolymerisation, Dinuelear Copper Complexes, Diastereomers, X-Ray | | | |
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| default:Reihe_B/49/ZNB-1994-49b-1410.pdf | | | | Identifier
| ZNB-1994-49b-1410 | | | | Volume
| 49 | |
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