| | 1 | Author
| HerbertW. Roesky, Wilfried Schmieder, Klaus Ambrosius | Requires cookie* | | | Title
| Über Additionsreaktionen von zinnorganischen Verbindungen mit N.N' -Bis(pentafluorphenyl)-sehwefeldiimid Addition Reactions of Tinorganic Compounds with N,N'-Bis(pentafluorophenyl)sulfurdiimide  | | | | Abstract
| The reactions of N,N / -bis(pentafluorophenyl)sulfurdiimide with [(CH3)3Sn]2NCH3, [(CH3)3Sn]3N and [(CHg^SnJaNCeFs yiels the 1:1 adducts 1-3. *H and 19 F NMR investiga-tions show, that fluorine atoms in the ortho position of the phenyl ring coordinate to the tin atom. This causes an increase of electron density at tin. A similar interpretation is given for the adduct 4 of N,N'-bis(^-chlorophenylsulfonyl)sulfurdiimide and [(CH3)3Sn]2NCH3, where an oxygen atom of the sulfonyl group is bonded to tin. | | | |
Reference
| Z. Naturforsch. 34b, 197—199 (1979); eingegangen am 28. September 1978 | | | |
Published
| 1979 | | | |
Keywords
| Pentafluorophenyl Derivatives, Tin, Coordination Compounds | | | |
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| default:Reihe_B/34/ZNB-1979-34b-0197.pdf | | | | Identifier
| ZNB-1979-34b-0197 | | | | Volume
| 34 | |
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