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'Coordination Chemistry' in keywords Facet   Publication Year 1981  [X]
Facet   section ZfN Section B  [X]
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1Author    Helmut Burdorf, Christoph EischenbroichRequires cookie*
 Title    Metall-rr-Komplexe yon Benzolderivaten, XIII [1] Bis(methylthio-/-beiizol)chrom(0) Darstellung und Einsatz als zweizähniger Chelatligand  
 Abstract    The thioanisole-7r-complexes (methylthio-^-benzene)-(^-benzene)-chromium (2) and bis(methylthio-r/-benzene)chromium (3) have been prepared via lithiation of bis(rj-benzene)-chromium and consecutive reaction with dimethyldisulfide. *H NMR and 13 C NMR spectra of 2 and 3 as well as ESR-spectra of the corresponding radical cations 2t and 3t were recorded and analyzed. In contrast to C(»?.arene)-Si and C(r/-arene)-P bonds, C(1/.arene)-S bonds are stable to solvolysis. With (norbornadiene)tetracarbonylmolybdenum, 3 readily forms [bis(methylthio-?j-benzene)chromium]tetracarbonylmolybdenum (6) wherein 3 functions as a chelating ligand. *H and 13 C NMR evidence suggests, that at room temperature 6 undergoes rapid conformational interconversions. 
  Reference    (Z. Naturforsch. 36b, 94—101 [1981]; eingegangen am 9. September 1980) 
  Published    1981 
  Keywords    Thioanisole Sandwich Complexes, X H NMR Spectra, 13 C NMR Spectra, ESR Spectra, Coordination Chemistry 
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 TEI-XML for    default:Reihe_B/36/ZNB-1981-36b-0094.pdf 
 Identifier    ZNB-1981-36b-0094 
 Volume    36