| 1 | Author
| T. Hashimoto, M. Tori, Y. Asakawa, E. Wollenweber | Requires cookie* | | Title
| Synthesis of Two Allergenic Constituents of Propolis and Poplar Bud Excretion  | | | Abstract
| The prenyl ester and the phenylethyl ester of caffeic acid, formed in the bud excretion of poplar species, were shown recently to be the major contact allergens in bee-glue. An unambiguous synthesis of these compounds, based on the reaction of caffeic acid with l-bromo-3-methyl-2-butene and with ß-bromoethylbenzene, respectively, is reported. The synthetic products confirm the previously described structures of the natural products and allow further testing of their allergenic properties. | | |
Reference
| Z. Naturforsch. 43c, 470—472 (1988); received January 25 1988 | | |
Published
| 1988 | | |
Keywords
| Propolis, Contact Allergens, Prenyl Caffeate, Phenylethyl Caffeate, Synthesis | | |
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| default:Reihe_C/43/ZNC-1988-43c-0470_n.pdf | | | Identifier
| ZNC-1988-43c-0470_n | | | Volume
| 43 | |
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