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1986 (1)
1Author    JankoN. Herak, Günter BehrensRequires cookie*
 Title    An in-situ Electron Spin Resonance Study  
 Abstract    ESR spectroscopy has been used to analyse the conformation of the radicals produced by the reaction of SOj with D-ribose (1), and 2-deoxy-D-ribose (6), at pH 1.3-5. From ribose three different types of radicals formed by H abstraction at C -l, C-2 and C-3 followed by a regio-selective a,ß-water elimination have been identified: the 2-deoxy-ribonolacton-2-yl (3), the 1-deoxy-pentopyranos-2-ulos-l-yl (4). and the 4-deoxy-pentopyranos-3-ulos-4-yl (2). Using deoxyribose two radicals of similar type, formed by H abstraction at C-3 and C-4 followed by water elimination, have been observed: the 2,4-dideoxy-3-ulos-4-yl (7) and the 2,3-dideoxy-4-ulos-3-yl (8). In addition, from both sugars an a-hydroxyalkyl radical has been identified based in part on the timing of their conformational motions: the ribos-3-yl (5) (the precursor of 2) and the 2-deoxy-ribos-l-yl (9), respectively. For radical 5 the rate constant k(e) for the water elimination and hence transformation into radical 2 was estimated. From the analysis of selective line broadening the frequencies of conformational changes of radicals 2 and 7 have been estimated. For 7 the frequencies of exchange of the two methylene groups were found to differ by more than 3 orders of magnitude. 
  Reference    Z. Naturforsch. 41c, 1062 (1986); received January 31 1986 
  Published    1986 
  Keywords    Free Radicals, Deoxy-D-ribose, D-Ribose, Conformational Kinetics, Electron Spin Resonance 
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 TEI-XML for    default:Reihe_C/41/ZNC-1986-41c-1062.pdf 
 Identifier    ZNC-1986-41c-1062 
 Volume    41