| | 1 | Author
| Ralf Steudel, Jürgen Steidel, Torsten Sandow | Requires cookie* | | | Title
| Preparation and Crystal Structure of £7s-Tetrachlorobis(cycIooctasulfurmonoxide)tin(IV) [1]  | | | | Abstract
| Yellow crystals of c/s-[SnCl4(S8 0) 2] containing the homocyclic sulfur oxide S80 have been prepared from the com ponents in carbon disulfide at —35 °C. A n X-ray structural analysis carried out at —105 °C showed the com pound to be monoclinic, space group P2 Jn with Z = 4 in a unit cell of dimensions a = 821.2(2) pm, b = 1331.9(4) pm , c = 2071.7(6) pm and ß -91.82(2)°. The structure was refined to a final agreem ent factor R = 0.038 for 2022 reflections. The tin atom is surrounded by a distorted octahedron of two oxygen atom s in cw-positions and four chlorine atom s in accordance with other oxygen-bonded complexes of SnCl4. The molecular symmetry is approximately C2, and the SS bond lengths in the ligands vary betw een 201 and 218 pm. V ibra tional spectra of [SnCl4 (SH 0) 2] are reported. The title com pound is the second example containing S80 as a ligand. | | | |
Reference
| Z. Naturforsch. 41b, 951 (1986); received April 29 1986 | | | |
Published
| 1986 | | | |
Keywords
| Sulfur Oxides, Tin T etrachloride, Crystal Structure, Complex Form ation, V ibrational Spectra | | | |
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| default:Reihe_B/41/ZNB-1986-41b-0951.pdf | | | | Identifier
| ZNB-1986-41b-0951 | | | | Volume
| 41 | |
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