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'Cobalt Schiff Base Complex' in keywords
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1993 (1)
1Author    Emerich Eichhorn, Anton Rieker, Bernd Speiser, Jürgen Sieglen, Joachim SträhleRequires cookie*
 Title    Electrochemistry of Oxygenation Catalysts, Part 2 + Improved Synthesis, Crystal Structure, and Electrochemical Properties of N,N-Bis(salicylidene)ethylenediaminatocobalt(III) Chloride  
 Abstract    N,N'-Bis(salicylidene)ethylenediaminatocobalt(III) hydroxide is treated with chloroform in methanol to yield the corresponding chloride in pure, crystalline form. Results of the crystal structure determination compare well with those in earlier reports of dimeric [Co(salen)Cl]2 units and incorporated CHC13 molecules. Electrochemical experiments in D M F and pyridine show that the chloride fully dissociates in these donor solvents. Thus, the quasireversible one-electron reduction to Co(salen) is observed in cyclic voltammograms. 
  Reference    Z. Naturforsch. 48b, 418—424 (1993) 
  Published    1993 
  Keywords    Oxygenation Catalyst, Cobalt Schiff-Base Complex, Crystal Structure, Electrochemistry 
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 TEI-XML for    default:Reihe_B/48/ZNB-1993-48b-0418.pdf 
 Identifier    ZNB-1993-48b-0418 
 Volume    48