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1983 (1)
1Author    Kurt Klepp, Weif BrongerRequires cookie*
 Title    Na6CoS4 -ein Thiocobaltat mit isolierten CoS4-Anionen Na6CoS4 -A Thiocobaltate with Isolated C0S4 Anions  
 Abstract    NaeCoS4 crystallizes in the hexagonal space group P 63111c with a —890.9(2) pm and c = 687.8(2) pm, Z = 2. The crystal structure was determined from four circle diffracto-meter data and refined to a conventional .ff-value of 0.020. NaöCoS4 is isotypic with NaeZnC>4. The crystal structure can be derived from a h.c.p. arrangement of S atoms. Co atoms occupy tetrahedral voids, the resulting CoS4-tetrahedra being almost regular with an average Co-S distance of 235 pm. Na atoms occupy tetrahedral and octahedral voids in the ratio 1:1. 
  Reference    (Z. Naturforsch. 38b, 12—15 [1983]; eingegangen am 27. August 1982) 
  Published    1983 
  Keywords    Crystal Structure, Ternary Chalcogenides, Cobalt Compounds 
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 TEI-XML for    default:Reihe_B/38/ZNB-1983-38b-0012.pdf 
 Identifier    ZNB-1983-38b-0012 
 Volume    38