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2001 (2)
1Author    Shao-Yi Wu, Wen-Chen ZhengRequires cookie*
 Title    Theoretical Studies of the g Factors for Co2+ in MgO and CaO Crystals  
 Abstract    This paper presents a cluster approach to the calculation of the g factors for 3d7 ions in cubic oc­ tahedral crystals, in which the parameters related to the configuration interaction and the covalency reduction effects are obtained from optical spectra of the studied crystals, and so no adjustable parameters are applied. From the approach, the g factors for MgO:Co2+ and CaO:Co2+ are cal­ culated. The calculated results show good agreement with the observed values. The experimental values of g < 4.333 (the first order value in absence of configuration and covalency interactions) for MgO:Co2+ and g > 4.333 for CaO:Co2+ are also explained. 
  Reference    Z. Naturforsch. 56a, 249—252 (2001); received October 13 2000 
  Published    2001 
  Keywords    Electron Paramagnetic Resonance (EPR), Crystal-field Theory, Co2+ Ion, MgO, CaO 
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 TEI-XML for    default:Reihe_A/56/ZNA-2001-56a-0249.pdf 
 Identifier    ZNA-2001-56a-0249 
 Volume    56 
2Author    W. Ua, Wen-Chen ZhengaRequires cookie*
 Title    Local Lattice Distortion near Co2+ in SrLaA104 Crystal  
 Abstract    The local tetragonal distortion in the vicinity of substitutional Co2+ impurities in SrLaA104 crystal is studied by fitting the calculated EPR parameters g\\, g±, A\\ and A± to the observed values. The result shows that the local distortion is mainly due to the elongation of metal-ligand distance R± perpendicular to the C 4 axis. This point is consistent with the expectation based on the consideration of ionic radius sum. This smaller tetragonal distortion of the oxygen octahedron surrounding the Co2+ impurity than that in the host crystal is supported by the result obtained in Cr3+-doped SrLaA104 crystal. -P a cs: 61.70Rj; 76.30Fc; 71.70Ch 
  Reference    Z. Naturforsch. 56a, 557—560 (2001); received May 11 2001 
  Published    2001 
  Keywords    Defect structure, Electronic Paramagnetic Resonance (EPR), Crystal Field Theory, SrLaA104 Crystal, Co2+ Ion 
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 TEI-XML for    default:Reihe_A/56/ZNA-2001-56a-0557.pdf 
 Identifier    ZNA-2001-56a-0557 
 Volume    56