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1987 (1)
1Author    Karl Hensen, Jens GaedeRequires cookie*
 Title    Thermodynamische Interpretation der Schmelzdiagramme binärer Systeme aus Methylchlorsilanen und Pyridazin bzw. Pyrazin  
 Abstract    By analyzing the cooling curves and the resulting melting point diagrams of the chloro-methylsilane-pyridazine and pyrazine systems the existence of the incongruently melting addition compounds CH 3 SiCl 3 • Pyridazine, (CH 3) 2 SiCl 2 • (Pyridazine) 2 , (CH 3) 3 SiCl • (Pyridazine) 2 , CH 3 SiCl 3 • (Pyrazine) 2 , (CH 3) 2 SiCl 2 • (Pyrazine) 2 , (CH 3) 3 SiCl • (Pyrazine) 2 was proved. By electro-optical measurements of the turbidity point it was proved that the system (CH 3) 3 SiCl-Pyridazine exhibits a miscibility gap which intersects the liquidus curve of the amine. Based on certain approximations it was possible to fit thermodynamic functions to the experimental results to obtain the excess data of mixing of the corresponding systems. These data allow for a more profound understanding of the Lewis-acid base behaviour of the silanes and amines. A) Experimentelle Ergebnisse 
  Reference    Z. Naturforsch. 42a, 341—351 (1987); eingegangen am 23. Juli 1986 
  Published    1987 
  Keywords    Chloromethylsilanes, Pyridazine, Pyrazine, Phase Diagrams, Addition Compounds, Thermo-dynamic Excess Functions 
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 TEI-XML for    default:Reihe_A/42/ZNA-1987-42a-0341.pdf 
 Identifier    ZNA-1987-42a-0341 
 Volume    42