| | 1 | Author
| Rolf Appel, Und Volker, Ingo Gläsel | Requires cookie* | | | Title
| Isolierbare  | | | | Abstract
| Chlor [(thio)alkoxy] triorganylphosphoniumchloride als Zwischenprodukte der Oxiran (Thiiran)-Halogenierung mit Dichlorphosphoranen [1] Isolable Chloro[(thio)alkoxy]triorganylphosphoniumchlorides as Intermediates of the Oxirane (Thiirane)-Halogenation with Dichlorophosphoranes [1] Isolable chloro[(thio)alkoxy]triorganylphosphoniumchlorides RR2'P-X-CH2R"] + C1 _ are synthesized by reaction of oxiranes (2-5) (oxetane (6), thiiranes (18a-c)) with dichloro-phosphoranes (la-f). Structure and stability are discussed. Thermal Arbusov-rearrange-ment yields vicinal di-resp. trihalo-alkanes and phosphanoxides. The structures are confirmed by 3ip{iH} and isqiH} NMR data. | | | |
Reference
| Z. Naturforsch. 36b, 447—450 (1981); eingegangen am 12. Dezember 1980 | | | |
Published
| 1981 | | | |
Keywords
| Halogenation, Oxiranes, Thiiranes, Dichlorophosphoranes, Chloro[(thio)alkoxy]phosphonium Salts | | | |
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| default:Reihe_B/36/ZNB-1981-36b-0447.pdf | | | | Identifier
| ZNB-1981-36b-0447 | | | | Volume
| 36 | |
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