| 1 | Author
| Joachim Pickardt, Norbert Rautenberg | Requires cookie* | | Title
| Die Kristallstruktur von Hexa- The Crystal Structure of Hexa-^-chloro-/^- oxo-tetrakis [hexamethylenetetraminecopper- (II)], [Cu4Cl60(C6H12Nl)4], a Copper(II) Complex with a Structure Related to that of Beryllium Oxoacetate  | | | Abstract
| -tetrakis [hexamethy lentetramin -kupfer(II)], [CU4C160(C6H12N4)4], einem Kupfer(II)-Komplex mit Berylliumoxoace-tat-ähnlicher Struktur By reaction of solutions of CuCl2 • 2H20 and hexamethylenetetramine, C6H12N4, in acetone, a complex [Cu4Cl60(C6Hi2N4)] could be ob-tained as single crystals. An X-ray analysis shows that the complex has a structure related to that of basic beryllium acetate. An oxygen atom is tetrahedrally surrounded by four cop-per atoms which, together with six chlorine atoms, form an adamantane-like core. Each copper atom is bonded via a nitrogen atom to a hexamethylenetetramine molecule. | | |
Reference
| Z. Naturforsch. 37b, 1355—1357 (1982); eingegangen am 28. Juni 1982 | | |
Published
| 1982 | | |
Keywords
| Copper(II) Complexes, Chloro Complexes, Hexamethylenetetramine, X-ray | | |
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| 37 | |
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