| | 1 | Author
| Ernst Küsters, Willy Rahmen | Requires cookie* | | | Title
| Alio-Verbindungen mit ungewöhnlichem Verhalten bei der Gaschromatographie an chiraler stationärer Phase Allo-Compounds with Unusual Behaviour in Gas Chromatography Using Chiral Stationary Phase  | | | | Abstract
| The Separation of the enantiomers of D,L-allo-threoninol, necessary in racemization studies of peptide hydrolysates, gave a surprising result with respect to the elution series of the antipodes. Contrary to the rule (L before D on Chirasil-L-Val) D-allo-threoninol is eluted before its mirror image. This behaviour can only be explained by the differing importance of the asymmetric centres contained in the molecule. As a result of this and taking into account the chromatographic behaviour of allo-compounds refined model concepts of enantiomer separation must be devel-oped in future. The separation of allo-compounds of threonine, isoleucine and cystathionine is considered from this aspect. | | | |
Reference
| Z. Naturforsch. 43b, 619—622 (1988); eingegangen am 15. April/30. November 1987 | | | |
Published
| 1988 | | | |
Keywords
| Enantiomeric Separation, Gaschromatography, Chirasil-Val, Allo-Compounds, Chiral Recognition | | | |
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| default:Reihe_B/43/ZNB-1988-43b-0619.pdf | | | | Identifier
| ZNB-1988-43b-0619 | | | | Volume
| 43 | |
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