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'Chiral Bis phosphine Reduction of P O' in keywords Facet   section ZfN Section B  [X]
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1995 (1)
1Author    LutzD. Ahlenburg, A.Lexander WolskiRequires cookie*
 Title    Oligophosphan-Liganden, XXXIX*  
 Abstract    (lS,2S)-fraw s-C yclopentan-l,2-diyl-bis(phosphan), C5H 8(P H 2)2? durch Reduktion eines diastereomerenreinen Cyclopentandiyl-bis(dioxaphospholans) O ligophosphine Ligands, X X X IX . (1 5,25')-rra/t5-C yclopentane-l,2-diyl-bis(phosphine), C5FI8(P H 2)2, by R eduction of a D iastereom erically Pure C yclopentanediyl-bis(dioxaphospholane) C hristine E ckert, The title compound (S, S)-2, has been obtained by reduction with Li[A lH 4] o f the cyclopen-tane-l,2-diyl-bis(l',3',2'-dioxaphospholane) (1 5 ,2 S)-frans-C5H 8[P (0 C H (C 0 2Pr-/)-(/ ?) -)2]2, (S, 5")-l, which itself was isolated in diastereomerically pure form (X-ray structure analysis) from the reaction between rac, /rfl«s-CsH8(PCl2)2 and (2 /? ,3 /?)-(+)-d iiso p ro p y l tartrate. C l e a v a g e o f (S ,.S)-1 w i t h P C U y i e l d e d a n u n s e p a r a b l e m i x t u r e o f (1 S , 2 S W r a n s -C 5 H 8(P C l 2) 2 a n d (4 R .5 R) -C l P [ 0 C H (C 0 2P r -t) -]2. 
  Reference    Z. Naturforsch. 50b, 1004—1008 (1995); eingegangen am 30. N ovem ber 1994 
  Published    1995 
  Keywords    Chiral Bis(phosphine) Reduction of P -O, X-Ray, Mass Spectra, NM R Spectra 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-1004.pdf 
 Identifier    ZNB-1995-50b-1004 
 Volume    50