| | 1 | Author
| J. Feller3, H. Oppermann3, R. Kucharkowskib, S. Däbritzc | Requires cookie* | | | Title
| Phasenbeziehungen und Chemischer Transport der Verbindungen im ternären System Re/Mo/O Phase Relations and Chemical Transport of the Compounds in the Ternary System Re/Mo/O  | | | | Abstract
| In the ternary system Re/Mo/O four series of mixed oxides have been prepared by heating of powder samples and by transport reactions. The series are derived from the oxides R e 0 2, M o 0 2, 7 -Mo4O u und //-Mo40 |i and have compositions R e1_ vM ov0 2 (0 < x < 0.37), M o,_> .Re>0 2 (0 < v < 0 .4 2),7 -M o 4_-| Re-| 0 11 (0 < Zj < l),a n d /7-Mo4_.2Re-^Ö |, (0 < z 2 < 1). Contributions to the understanding of the transport mechanism were obtained from thermodynamic calculations. The composition of the mixed crystals obtained have been determined by EPM A and ICP-AES. | | | |
Reference
| Z. Naturforsch. 53b, 397—104 (1998); eingegangen am 21. Januar 1998 | | | |
Published
| 1998 | | | |
Keywords
| Rhenium Molybdenum Mixed Oxides, Chemical Transport Reaction, Phase Diagram | | | |
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| default:Reihe_B/53/ZNB-1998-53b-0397.pdf | | | | Identifier
| ZNB-1998-53b-0397 | | | | Volume
| 53 | |
| 2 | Author
| J. Feller1, H. Oppermann, M. Binnewiesb, E. Milkeb | Requires cookie* | | | Title
| On the Chemical Transport o f Rhenium and Rhenium Oxides | | | | Abstract
| Synthesis and single crystal growth by chemical transport reactions o f rhenium and rhenium oxides is reported. Several transport agents like the mercury halides H gC l2, HgBr2, H g l2, tellurium tetrachloride and iodine have been employed the transport o f the rhenium compounds. Mass spectrometric experiments gave informations about the composition o f the gas phase. The transport reactions were traced by calculations based on the knowledge o f the gas phase species and their thermodynamical data. | | | |
Reference
| Z. Naturforsch. 53b, 184—190 (1998); eingegangen am 7. November 1997 | | | |
Published
| 1998 | | | |
Keywords
| Chemical Transport Reaction, Rhenium Oxides, Thermodynamic Calculation, Mass Spectra | | | |
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| default:Reihe_B/53/ZNB-1998-53b-0184.pdf | | | | Identifier
| ZNB-1998-53b-0184 | | | | Volume
| 53 | |
| 3 | Author
| Oppermann, S. Herrera, DaoQuoc Huong | Requires cookie* | | | Title
| Untersuchungen zum chemischen Transport von YX3 mit A1X3 und zur Existenz von gasförmigen und festen Komplexen YA13 X12 (X = Br, I) Investigations on the Chemical Transport Reaction of YX3 with A1X3 and on the Existence of Gaseous and Solid Complexes YA13 X 12 (X = Br, I) H | | | | Abstract
| The dominant gaseous complexes YAl3B r12 and YA13I 12 were generated in the chemical trans port reactions of YBr3 with AlBr3 and YI3 with A1I3. The enthalpy of formation Z\H£(YAl3B r12,gi298) = -484,5 ± 6 kcal/mol and the standard entropy S°(YA13B 12 g 298) = 290,0 ± 7,5 cal/K mol have been calculated. It follows from total pressure measurements of mixtures of YBr3 s with AlBr3 1 and YI3 s with A1I3 b respectively, that complexes YAl3B r12 s and YA13I 12 s do not exist up to the boiling points of the aluminium trihalides. | | | |
Reference
| Z. Naturforsch. 53b, 361—366 (1998); eingegangen am 1. Dezember 1997 | | | |
Published
| 1998 | | | |
Keywords
| Chemical Transport Reaction, Yttrium Aluminium Halides, Enthalpy of Formation, Standard Entropy, Total Pressure Measurements | | | |
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| default:Reihe_B/53/ZNB-1998-53b-0361.pdf | | | | Identifier
| ZNB-1998-53b-0361 | | | | Volume
| 53 | |
| 4 | Author
| H. Oppermann, B. Marklein | Requires cookie* | | | Title
| | | | | Abstract
| The heterogeneous reactions: 0 s 0 4 s = 0 s 0 4 g, 2 0 s 0 2,s = Oss + 0 s 0 4 g, Oss + 3 0 s 0 4 g = 4 0 s 0 3 g, 0 s 0 2s + 0 s 0 4 g = 2 0 s 0 3 g and the homogeneous reaction 0 s 0 4 " = 0 s 0 3 g + '/2 0 2 g were determined by total pressure measurements. From this and from chemical transport reactions of 0 s 0 2 and Os with Osmium tetroxide, the enthalpy of formation of gaseous 0 s 0 3 was computed to Z\H ß(0s03 g i98) = -40,0 ± 3 kcal/mol. | | | |
Reference
| Z. Naturforsch. 53b, 1352—1364 (1998); eingegangen am 3. Juli 1998 | | | |
Published
| 1998 | | | |
Keywords
| Osmium Oxides, Chemical Transport Reactions, Total Pressure Measurements, Enthalpy of Formation, Standard Entropy | | | |
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| default:Reihe_B/53/ZNB-1998-53b-1352.pdf | | | | Identifier
| ZNB-1998-53b-1352 | | | | Volume
| 53 | |
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