| | 1 | Author
| Volker Küllmer, Erika Röttinger, Heinrich Vahrenkamp | Requires cookie* | | | Title
| Oxidation von Mercapto-Carbonyl-Mangankomplexen Oxidation of Mercapto Carbonyl Manganese Complexes  | | | | Abstract
| Chemical oxidation of the mercapto carbonyl manganese complexes (Me3P)2(CO)3Mn-SX (1), (Me3P)2(CO)5Mn2(SX)2 (2), and (CO)8Mn2(SX)2 (3) (X = H, SnMe3) were investigated. From the SH complexes no identifiable products could be obtained. For X = SnMe3, the iodine oxidation of 2 yielded (Me3P)2(CO)5Mn2S2 (5), that of 3 gave (CO)i5Mn4S4 (7), both containing bridging disulfide ligands. The crystal structure of 7 was determined. | | | |
Reference
| Z. Naturforsch. 34b, 224—229 (1979); eingegangen am 29. September 1978 | | | |
Published
| 1979 | | | |
Keywords
| Chemical Oxidation, Mercapto Ligands, Disulfide Ligands, Crystal Structure | | | |
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| default:Reihe_B/34/ZNB-1979-34b-0224.pdf | | | | Identifier
| ZNB-1979-34b-0224 | | | | Volume
| 34 | |
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