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1Author    A. P. Jekel, J. C. Van De GrampelRequires cookie*
 Title    Derivatives of eis-NPC12(NS0C1)2 and (NPC12)2NS0C1, Part XII [1] Triphenylphosphazenyl Derivatives of NPC12(NS0X)2 and (NPC12)2NS0X with X = F, Cl or Ph  
 Abstract    Reaction of the ring systems NPC12(NS0X)2 and (NPC12)2NS0X (X = F, Cl, Ph) with HNPPI13 in molar ratio 1:2 gives their mono(tripbenylphosphazenyl) derivatives. The compound NPCl(NPPh3)(NSOPh)2 forms a stable 1:1 adduct with acetonitrile. All compounds are characterized by NMR (31 P, 19 F), IR and mass spectra. 
  Reference    Z. Naturforsch. 34b, 569—572 (1979); received December 27 1978 
  Published    1979 
  Keywords    Triphenylphosphazenyl Derivatives, Preparation, Characterization 
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 TEI-XML for    default:Reihe_B/34/ZNB-1979-34b-0569.pdf 
 Identifier    ZNB-1979-34b-0569 
 Volume    34 
2Author    Hidenari Inoue, Ekkehard FluckRequires cookie*
 Title    Darstellung und Charakterisierung von Berlinerblau-Analoga des Typs Ti[MB(CN)6] Preparation and Characterization of Prussian Blue Analogs of the Type Ti[MB(CN)6]  
 Abstract    Three compounds of the type Ti[MB(CN)6] (MB = Co, Rh, and Ir) have been synthesized and characterized by means of their X-ray diffraction powder patterns, magnetic measurements, infrared, electronic, and X-ray photoelectron spectra. All compounds crystallize in the face-centered cubic system and form a three-dimensional framework of two octahedral coordination units MBC6 and TiN6. Upon the formation of Ti[MB(CN)6] from the corresponding potassium salt, the jz back-donation in the [MD(CN)6]3-moiety is enhanced by the bridge formation through the cyanide ligand. 
  Reference    Z. Naturforsch. 39b, 185 (1984); eingegangen am 12. Oktober 1983 
  Published    1984 
  Keywords    Preparation, Characterization, Prussian Blue Analogs 
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 TEI-XML for    default:Reihe_B/39/ZNB-1984-39b-0185.pdf 
 Identifier    ZNB-1984-39b-0185 
 Volume    39 
3Author    Requires cookie*
 Title    Darstellung und Charakterisierung eines Di-w-amido-und von Di-^-hydroxokomplexen der  
 Abstract    Zusammensetzung [n>C5H5 Cr(NO)(NH2) ] 2 bzw. [7t-C5H 5Cr(NO)(OH)]2 (H 20) n (n = 0 -2) S ynthesis and C haracterization o f a D i-^-am ido-and D i-^-hydroxo Com plexes o f C om position [7r-C5H 5C r(N O)(N H 2)]2 and |>r-C5H 5Cr(NO)(OH)]2 • (H 20)" {n = 0 -2), R esp ectively G e r h a r d H o c h , H a n s -E c k a r d S a s s e und M a n f r e d L. Z i e g l e r The title compounds have been synthesized and characterized by elementary analysis, IR and NMR methods and their mass spectra. The compound [7i-C5H 5 Cr(NO)(NH2) ]2 is a di-^-amido complex, [jr-C5H 5Cr(NO)(OH) ] 2 -2 H 20 is its hydroxo analogon, elevation of the temperature causes the stepwise loss of the two water molecules yielding [7r-C5H 5 Cr(N0)(0 H)]2 -H 2 0 and [7i-C5H 5Cr(NO)(OH)]2. 
  Reference    (Z. Naturforsch. 30b, 704—709 [1975]; eingegangen am 24. Juni 1975) 
  Published    1975 
  Keywords    Synthesis, Characterization, Di-^-amido Complexes, Di-^-hydroxo Complexes 
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 TEI-XML for    default:Reihe_B/30/ZNB-1975-30b-0704.pdf 
 Identifier    ZNB-1975-30b-0704 
 Volume    30 
4Author    Dieter Mohr, Henning Wienand, ManfredL. Ziegler, M-O-S-RM. M—s—r, M. M. S—r, VsRequires cookie*
 Title    Darstellung und Charakterisierung von Sulfinatokomplexen 7r-C7H7Mo(C0)2S02R (R=-C6H5, -C6H4CH3) sowie von ein-und zweikernigen Thioarylverbindungen der Zusammensetzung 7r-C7H7Mo(CO)2SR' bzw. [^-C7H7Mo(CO)SR ]2 (R =-S-C6H5, -S-C6H4CH3, -S-C6F5, -S-C6H4N02)  
 Abstract    Synthesis and Characterization of Sulfinato Complexes 7r-C7H7Mo(C0)2S02R (R = -C6H5, -C6H4CH3) and of Mono and Dinuclear Thioaryl Compounds of Composition TT-C7H7MO(CO)2SR' resp. 0t-C7H7Mo(CO)SR']2 (R' = The aryl-sulfinato complexes ?r-C7H7Mo(CO)2S02R have been synthesized by re-action of JI-C7H7MO(CO)2J with the Ag-SC>2-R compounds. The sulfinate group is S-bonded. Mononuclear and dinuclear thioaryl complexes were isolated by reaction of 7r-C7H7Mo(CO)2Br with aryl mercaptanes R'-S-H in the presence of (CaHs^N which functioned as a proton acceptor. IR data indicate the dependence of the 7t-acceptor abilities of the sulfur atom from R'. Der Sulfinatrest -SO2-R kann sowohl als ein-zähniger als auch als zweizähniger Ligand fungieren. Als einzähniger Ligand kann er sowohl über das Schwefelatom (Sulfinato-S-Komplex) als auch über ein Sauerstoffatom (Sulfinato-O-Komplexe) gebun-den sein 1 . 0 0 0 0—s—0 II II /\ / \-o 7 Als zweizähniger Ligand ist die R-SCVGruppe intra-bzw. intermolekular an das Zentralatom koordiniert 1 . Die Darstellung der Sulfinatokomplexe gelingt im allgemeinen durch direkte Einschiebung von SO2 in eine Metall-Kohlenstoffbindung z.B. gemäß 2 -3 : 
  Reference    (Z. Naturforsch. 31b, 66—72 [1976]; eingegangen am 29. Juli 1975) 
  Published    1976 
  Keywords    Synthesis, Characterization, Sulfinato Complexes, Thiaryl Complexes 
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 TEI-XML for    default:Reihe_B/31/ZNB-1976-31b-0066.pdf 
 Identifier    ZNB-1976-31b-0066 
 Volume    31 
5Author    Michael Kopp, LuiseR. Krauth, Richard Ratka, Klaus Weidenhammer, ManfredL. ZieglerRequires cookie*
 Title    Darstellung und Charakterisierung von 1.4-und 1.5-Dienkomplexen des Platins  
 Abstract    Röntgenstrukturanalyse von Diehloro-2.5-diphenyl-1.5-hexadienplatin(II), Cl2Pt((C6H5)2C6H8) Preparation and Characterization of 1,4-and 1,5-Diene Complexes of Platinum; X-ray Analysis of Dichloro-2,5-diphenyl-l,5-hexadiene Platinum(II), ((C^P^CöHs^CßHs) The reaction of cis-(C6H5CN)2PtCl2 and Na2PtCl4 with the dienes 1,4-pentadiene and 2,5-diphenyl-l,5-hexadiene yields the species eis-(1,4-pentadiene) PtCl2 and cis-(2,5-diphenyl-l,5-hexadiene)PtCl2, respectively. The compounds have been fully characterized by elemental analysis, IR, 1 H-NMR, mass spectroscopy and by X-ray methods. 
  Reference    Z. Naturforsch. 35b, 802—807 (1980); eingegangen am 29. Februar 1980 
  Published    1980 
  Keywords    Synthesis, Characterization, X-ray, Diene Complexes of Platinum 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-0802.pdf 
 Identifier    ZNB-1980-35b-0802 
 Volume    35 
6Author    Kurt Drewelies, Volker Münch, Jochen Jander, HansPeter LatschaRequires cookie*
 Title    O.O-Diphenyl-N-chloramidophosphat 0,0-Diphenyl-N-chlorophosphoramidate  
 Abstract    (C6H50)2P(0)NHC1 can be synthesized in 83-88% yield by direct hydrolysis of (C6H50)2P(0)NCl2 in petroleumether solution. This first example of a new class of N-halogeno compounds, a colourless crystalline substance was characterized by 31 P and X H NMR, IR and mass spectroscopy as well as by elemental analysis. 
  Reference    Z. Naturforsch. 35b, 1389—1390 (1980); eingegangen am 19. Juni 1980 
  Published    1980 
  Keywords    Synthesis, Characterization, 0, 0-Diphenyl-N-chlorophosphoramidate 
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 TEI-XML for    default:Reihe_B/35/ZNB-1980-35b-1389.pdf 
 Identifier    ZNB-1980-35b-1389 
 Volume    35