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1984[X]
1Author    Hidenari Inoue, Ekkehard FluckRequires cookie*
 Title    Darstellung und Charakterisierung von Berlinerblau-Analoga des Typs Ti[MB(CN)6] Preparation and Characterization of Prussian Blue Analogs of the Type Ti[MB(CN)6]  
 Abstract    Three compounds of the type Ti[MB(CN)6] (MB = Co, Rh, and Ir) have been synthesized and characterized by means of their X-ray diffraction powder patterns, magnetic measurements, infrared, electronic, and X-ray photoelectron spectra. All compounds crystallize in the face-centered cubic system and form a three-dimensional framework of two octahedral coordination units MBC6 and TiN6. Upon the formation of Ti[MB(CN)6] from the corresponding potassium salt, the jz back-donation in the [MD(CN)6]3-moiety is enhanced by the bridge formation through the cyanide ligand. 
  Reference    Z. Naturforsch. 39b, 185 (1984); eingegangen am 12. Oktober 1983 
  Published    1984 
  Keywords    Preparation, Characterization, Prussian Blue Analogs 
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 TEI-XML for    default:Reihe_B/39/ZNB-1984-39b-0185.pdf 
 Identifier    ZNB-1984-39b-0185 
 Volume    39