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'Cesium' in keywords Facet   section ZfN Section B  [X]
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1Author    KurtO. Klepp, G. Erald GablRequires cookie*
 Title    Preparation and Crystal Structure O f € 8 4 ^ 2 8 ! i  
 Abstract    The new polychalcogenide Cs4N b2Su was pre­ pared from the melt. Cs4Nb7Sn is orthorhombic, 0 P68, s.g. Pca2, (N o.29), Z = 4 with a = 13.775(9) Ä , b = 8.043(9) A , c = 18.306(5) A. The crystal structure was determ ined from diffractometer data and refined to a conventional R of 0.052 
  Reference    Z. Naturforsch. 53b, 1236—1238 (1998); received April 14 1998 
  Published    1998 
  Keywords    Chalcogenide, Thioniobate, Polysulfide, Niobium, Cesium 
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 TEI-XML for    default:Reihe_B/53/ZNB-1998-53b-1236_n.pdf 
 Identifier    ZNB-1998-53b-1236_n 
 Volume    53 
2Author    A. Nja-V, M. Erena, M. Udring, Artin JansenRequires cookie*
 Title    Darstellung und Kristallstruktur von Cs6Cl40 P rep aratio n and Crystal S tructure of Cs6Cl40  
 Abstract    The solid state synthesis and the crystal struc­ ture of Cs6Cl40 (Pearson-code hR22, R3c, a = 1324.7(6), c -1658(1) pm, Z -6, 931 reflections with I0 > 2a(I), R\ = 0.040, wR2 = 0.114) are repor­ ted. The compound crystallises isotypically with Rb6Cl40 in the anti-K4CdCl6 type of structure. The structure consists of infinite chains of alterna­ ting face-sharing OCs6 octahedra and ClCs6 trigo­ nal prisms which are separated by chloride anions. The underlying structural concept and the ana­ logy to perovskites are outlined. 
  Reference    Z. Naturforsch. 56b, 209—212 (2001); eingegangen am 2.November 2000 
  Published    2001 
  Keywords    Cesium, Halide, Solid State Synthesis 
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 TEI-XML for    default:Reihe_B/56/ZNB-2001-56b-0209_n.pdf 
 Identifier    ZNB-2001-56b-0209_n 
 Volume    56 
3Author    M. Schnock+, P. BöttcherRequires cookie*
 Title    Darstellung und Kristallstruktur von [Cs4(Dibenzo-18-Krone-6)3](S6)2-2CH3CN Synthesis and Crystal Structure of [Cs4(Dibenzo-18-Krone-6)3](S6)2 * 2 CH3CN  
 Abstract    [Cs4(dibenzo-18-crown-6)3](S6)2-2CH3CN has been prepared from dibenzo-18-crown-6, Cs2C 0 3 and suifur in acetonitrile saturated with H 2S. The title compound crystallizes in space group P I (lattice dimensions: a = 10,507(7)Ä, b = 11,504(6) A, c = 17,792(9) A, a = 97,86(4)°, ß = 105,86(4)°, y = 101,48(5)°) with one formula unit. The crystallographic units are built of stacks of three crown ether molecules and two hexasulfide chains with the cations located between them. The conformation of the hexasulfide chains is all-cis. 
  Reference    Z. Naturforsch. 50b, 721—724 (1995); eingegangen am 15. Septem ber 1994 
  Published    1995 
  Keywords    Cesium, Crown Ether, Polysulfide, Crystal Structure 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-0721.pdf 
 Identifier    ZNB-1995-50b-0721 
 Volume    50 
4Author    M. Wachhold, W. S. SheldrickRequires cookie*
 Title    Methanolothermale Synthese von Cs4As2Te6, des ersten Alkalimetall- Telluridoarsenats mit As-As-und Te-Te-Bindungen Methanolothermal Synthesis of Cs4As2Te6, the First Alkali Metal Telluridoarsenate with As-As and Te-Te Bonds  
 Abstract    Reaction of Cs2C 0 3 and As2Te3 in methanol at 145°C affords the telluridoarsenate(II) Cs4As2Te(,. A trans conformation is observed for the centrosymmetric As2Te^~ anions, which consist of two t/>-tetrahedralo As(As)(Te2)Te units with a common As-As bond. The terminal As-Te distance of 2.554(2) A is much shorter than the As-Te distance of 2.691(2) A to the Te2 unit, which exhibits a Te-Te bond length of 2.744(2) A. Both of the independent cations are coordinated in an irregular manner by eight Te atoms. 
  Reference    Z. Naturforsch. 51b, 1235—1239 (1996); eingegangen am 29. April 1996 
  Published    1996 
  Keywords    Cesium, Telluridoarsenate(II), Methanolothermal Synthesis, Crystal Structure 
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 TEI-XML for    default:Reihe_B/51/ZNB-1996-51b-1235.pdf 
 Identifier    ZNB-1996-51b-1235 
 Volume    51 
5Author    KarstenF. Ischerl, F. Eldbaum-M, Petra Öller1, M. Vogta, W. Ichael, VolkerW. Achholdb, H. Inter11, Orst SabrowRequires cookie*
 Title    Die Kristallstruktur von CsNaTe The Crystal Structure o f CsNaTe  
 Abstract    The crystal structure of CsNaTe has been determined by X-ray diffraction of single crystals. The hygroscopic CsNaTe crystallizes in the tetragonal space group P4/nmm (Z = 2) with the cell parameters a = 527.6(1) and c = 847.8(2) pm. The structure was determined from 237 independent reflections by Patterson and Fourier methods {R] = 0.065; wR2 = 0.080). 
  Reference    Z. Naturforsch. 51b, 1576—1578 (1996); eingegangen am 10. Mai 1996 
  Published    1996 
  Keywords    Cesium, Sodium Ternary Tellurides, Crystal Structure 
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 TEI-XML for    default:Reihe_B/51/ZNB-1996-51b-1576.pdf 
 Identifier    ZNB-1996-51b-1576 
 Volume    51 
6Author    Sabine Schlecht, Soheila Chitsaz, Bernhard Neumüller, Kurt DehnickeRequires cookie*
 Title    Die Kristallstrukturen des Diphenylphosphinsäureamids, Ph2P(0)NH 2, und seines Cäsiumsalzes [Cs{Ph2P(0)NH}] Crystal Structures of Diphenylphosphinic Acid Amide, Ph-,P(0)NH-, and of its Cesium Salt [Cs{Ph2P(0)NH}]  
 Abstract    The crystal structures of the monoclinic form of Ph2P(0)NH2 and of its cesium salt, [Cs{Ph2P(0)NH}l have been determined by X-ray methods. Ph2P(0)N H 2: Space group P2,/c, Z = 16, lattice dimensions (-80°C): a = 2530.2(3), b = 858.9(2), c = 2135.5(3) pm, ß = 110.78(1)°, R , = 0.055. Diphenylphosphinic acid amide forms dimeric molecules via N-H- • O hydrogen bonds, the dimeric units again are associated via hydrogen bonds to form infinite double chains along the crystallographic c axis. [Cs{Ph2P(0)NH}]: Space group Pccn, Z = 8 , lattice dimensions (-83°C): a = 1262.8(1), b = 2632.3(2), c = 769.1(1) pm , R\ = 0.024. The compound is associated via Cs-O and Cs-N contacts along the crystallographic [001] axis forming a tubular arrangement. There are no hydrogen bonds. 
  Reference    (Z. Naturforsch. 53b, 17—22 [1998]; eingegangen am 3. November 1997) 
  Published    1998 
  Keywords    Phosphinic Acid Amide, Cesium, Crystal Structure 
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 TEI-XML for    default:Reihe_B/53/ZNB-1998-53b-0017.pdf 
 Identifier    ZNB-1998-53b-0017 
 Volume    53