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'Cesium' in keywords Facet   Publication Year 1995  [X]
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1Author    M. Schnock+, P. BöttcherRequires cookie*
 Title    Darstellung und Kristallstruktur von [Cs4(Dibenzo-18-Krone-6)3](S6)2-2CH3CN Synthesis and Crystal Structure of [Cs4(Dibenzo-18-Krone-6)3](S6)2 * 2 CH3CN  
 Abstract    [Cs4(dibenzo-18-crown-6)3](S6)2-2CH3CN has been prepared from dibenzo-18-crown-6, Cs2C 0 3 and suifur in acetonitrile saturated with H 2S. The title compound crystallizes in space group P I (lattice dimensions: a = 10,507(7)Ä, b = 11,504(6) A, c = 17,792(9) A, a = 97,86(4)°, ß = 105,86(4)°, y = 101,48(5)°) with one formula unit. The crystallographic units are built of stacks of three crown ether molecules and two hexasulfide chains with the cations located between them. The conformation of the hexasulfide chains is all-cis. 
  Reference    Z. Naturforsch. 50b, 721—724 (1995); eingegangen am 15. Septem ber 1994 
  Published    1995 
  Keywords    Cesium, Crown Ether, Polysulfide, Crystal Structure 
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 TEI-XML for    default:Reihe_B/50/ZNB-1995-50b-0721.pdf 
 Identifier    ZNB-1995-50b-0721 
 Volume    50